Semiclassical initial value approach for chaotic long-lived dynamics

被引:47
作者
Campolieti, G [1 ]
Brumer, P [1 ]
机构
[1] Univ Toronto, Dept Chem, Chem Phys Theory Grp, Toronto, ON M5S 3H6, Canada
关键词
D O I
10.1063/1.476892
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
A time-dependent initial value semiclassical propagator approach is developed and applied to the propagation of a two-dimensional quantum system whose classical counterpart is highly chaotic. The energy spectrum of a quartic oscillator, obtained from the propagated wavefunction, is shown to be accurately and simply computed by application of stationary-phase Monte Carlo integration. Chaotic trajectories are handled naturally, without giving rise to the singularities seen in other methods. (C) 1998 American Institute of Physics. [S0021-9606(98)00932-5].
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页码:2999 / 3003
页数:5
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