Conformational isomerism leads to supramolecular isomerism and nanoscale inclusion in 2D extended framework solids based on C-methylcalix[4]resorcinarene

被引:91
作者
MacGillivray, LR [1 ]
Reid, JL
Ripmeester, JA
机构
[1] Univ Iowa, Dept Chem, Iowa City, IA 52242 USA
[2] Natl Res Council Canada, Steacie Inst Mol Sci, Ottawa, ON K1A 0R6, Canada
关键词
D O I
10.1039/b102856c
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Co-crystallization of C-methylcalix[4]resorcinarene 1 with 4,4'-bipyridine 2 in the presence of m-xylene results in the formation of a 2D brick framework, 3c.2(m-xylene), that possesses nanoscale cavities that host four aromatics as guests in which 1 adopts a 'T-shaped' conformation.
引用
收藏
页码:1034 / 1035
页数:2
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