Conformational isomerism leads to supramolecular isomerism and nanoscale inclusion in 2D extended framework solids based on C-methylcalix[4]resorcinarene
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作者:
MacGillivray, LR
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Univ Iowa, Dept Chem, Iowa City, IA 52242 USAUniv Iowa, Dept Chem, Iowa City, IA 52242 USA
MacGillivray, LR
[1
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Reid, JL
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机构:Univ Iowa, Dept Chem, Iowa City, IA 52242 USA
Reid, JL
Ripmeester, JA
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机构:Univ Iowa, Dept Chem, Iowa City, IA 52242 USA
Ripmeester, JA
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[1] Univ Iowa, Dept Chem, Iowa City, IA 52242 USA
[2] Natl Res Council Canada, Steacie Inst Mol Sci, Ottawa, ON K1A 0R6, Canada
Co-crystallization of C-methylcalix[4]resorcinarene 1 with 4,4'-bipyridine 2 in the presence of m-xylene results in the formation of a 2D brick framework, 3c.2(m-xylene), that possesses nanoscale cavities that host four aromatics as guests in which 1 adopts a 'T-shaped' conformation.