The hydrothermal synthesis of the new manganese and vanadium oxides, NiMnO3H, MAV3O7 and MA0.75V4O10•0.67H2O (MA = CH3NH3)

被引:34
作者
Chen, RJ [1 ]
Zavalij, PY
Whittingham, MS
Greedan, JE
Raju, NP
Bieringer, M
机构
[1] SUNY Binghamton, Dept Chem, Binghamton, NY 13902 USA
[2] SUNY Binghamton, Mat Res Ctr, Binghamton, NY 13902 USA
[3] McMaster Univ, Brockhouse Inst Mat Res, Hamilton, ON L8S 4M1, Canada
[4] McMaster Univ, Dept Chem, Hamilton, ON L8S 4M1, Canada
关键词
D O I
10.1039/a805312j
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
The hydrothermal reaction of manganese or vanadium oxides in the presence of organic cations leads to the formation of new layered structures. When nickel salts are hydrothermally reacted with tetramethylammonium permanganate a new orthorhombic form of nickel manganese oxide, NiMnO3Hx (where x less than or equal to 1) is formed. It readily chemically intercalates lithium; it has space group Cmc2(1), a = 2.861(1) Angstrom, b = 14.650(1)Angstrom, and c = 5.270(1) Angstrom. The magnetic properties of this compound are quite different from the ilmenite NiMnO3 phase, showing paramagnetism above 390 K and more complex behavior below that temperature. The hydrothermal reaction of vanadium pentoxide with methylamine leads to a series of new layered vanadium oxides, which differ in structure from the corresponding ones prepared in the presence of the tetramethylammonium ion because of the existence of hydrogen bonding. Methylamine is the first organic to form a double sheet vanadium oxide, (CH3NH3)(0.75)V4O10. 0.67H(2)O, with the delta-AgxV2O5 structure. (CH3NH3)(0.75)V4O10. 0.67H(2)O is monoclinic, space group C2/m with a = 11.673( 1) Angstrom, b = 3.668( 1) Angstrom, c = 11.095(1) Angstrom and beta = 99.865(5)degrees. (CH3NH3)V3O7 shows significant buckling of the layers compared with N(CH3)(4)V3O7, and has a monoclinic unit cell, space group P2(1)/c with a =11.834(8) Angstrom, b = 6.663(4) Angstrom, c = 15.193(9) Angstrom and beta = 138.104(1)degrees.
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页码:93 / 100
页数:8
相关论文
共 44 条
  • [31] ROUXEL J, 1994, SOFT CHEM ROUTES NEW, V152
  • [32] SYNTHESIS AND STRUCTURAL INVESTIGATION OF A NEW POTASSIUM VANADIUM-OXIDE BRONZE - RHO-K0.50V2O5
    SAVARIAULT, JM
    GALY, J
    [J]. JOURNAL OF SOLID STATE CHEMISTRY, 1992, 101 (01) : 119 - 127
  • [33] THE HYDROTHERMAL SYNTHESIS OF NEW OXIDE MATERIALS
    WHITTINGHAM, MS
    GUO, JD
    CHEN, RJ
    CHIRAYIL, T
    JANAUER, G
    ZAVALIJ, P
    [J]. SOLID STATE IONICS, 1995, 75 : 257 - 268
  • [34] LITHIUM INTERCALATES OF TRANSITION-METAL DICHALCOGENIDES
    WHITTINGHAM, MS
    GAMBLE, FR
    [J]. MATERIALS RESEARCH BULLETIN, 1975, 10 (05) : 363 - 371
  • [35] WHITTINGHAM MS, 1994, MATER SCI FORUM, V152-, P99, DOI 10.4028/www.scientific.net/MSF.152-153.99
  • [36] YAMAMOTO N, 1986, J JAPAN SOC POWDER P, V33, P48
  • [37] LAYERED STRUCTURES OF VANADIUM PENTOXIDE GELS
    YAO, T
    OKA, Y
    YAMAMOTO, N
    [J]. MATERIALS RESEARCH BULLETIN, 1992, 27 (06) : 669 - 675
  • [38] Keggin cluster formation by hydrothermal reaction of tungsten trioxide with methyl substituted ammonium: The crystal structure of two novel compounds, [NH2(CH3)(2)]6H2W12O40 center dot similar to 4H(2)O and [N(CH3)(4)]6H2W12O40 center dot 2H(2)O
    Zavalij, P
    Guo, JD
    Whittingham, MS
    Jacobson, RA
    Pecharsky, V
    Bucher, CK
    Hwu, SJ
    [J]. JOURNAL OF SOLID STATE CHEMISTRY, 1996, 123 (01) : 83 - 92
  • [39] Layered tetramethylammonium vanadium oxide [N(CH3)(4)]V3O7 by X-ray Rietveld refinement
    Zavalij, PY
    Chirayil, T
    Whittingham, MS
    [J]. ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS, 1997, 53 : 879 - 881
  • [40] ZAVALIJ PY, 1998, IN PRESS ACTA CRYS B