A one-dimensional copper(II) coordination polymer containing [Fe(pytpy)2]2+ (pytpy=4′-(4-pyridyl)-2,2′: 6′,2"-terpyridine) as an expanded 4,4′-bipyridine ligand:: a hydrogen-bonded network penetrated by rod-like polymers

被引：44

作者：

Beves, Jonathon E. ^{[1
]}

Constable, Edwin C. ^{[1
]}

Housecroft, Catherine E. ^{[1
]}

Neuburger, Markus ^{[1
]}

Schaffner, Silvia ^{[1
]}

机构：

[1] Univ Basel, Dept Chem, CH-4056 Basel, Switzerland

来源：

CRYSTENGCOMM | 2008年 / 10卷 / 03期

关键词：

D O I：

10.1039/b713001e

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The one-dimensional coordination polymer [{(H2O)(NO3)(2)CuFe(1)(2)}(2)(NO3)(4)center dot 2.15MeCN center dot 5.85H(2)O](n) assembles when the pendant pyridine donors in [Fe(1)(2)](2+) (1 = 4'-(4-pyridyl)2,2': 6',2 ''-terpyridine) are treated with Cu(NO3)(2)center dot 3H(2)O, exemplifying [Fe(1)(2)](2+) as an expanded 4,4'-bipyridine ligand. In the solid state, the polymer chains are threaded through hydrogen-bonded macrocycles comprising coordinated and non-coordinated water molecules and nitrate ions, the macrocycles being motifs within interconnected sheets in the structure.

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页码：344 / 348

页数：5

相关论文

共 41 条

[1] SIR92 - a program for automatic solution of crystal structures by direct methods [J].

ALTOMARE, A ;

CASCARANO, G ;

GIACOVAZZO, G ;

GUAGLIARDI, A ;

BURLA, MC ;

POLIDORI, G ;

CAMALLI, M .

JOURNAL OF APPLIED CRYSTALLOGRAPHY, 1994, 27 :435-435

[2] Synthesis and pH-sensitive luminescence of bis-terpyridyl iridium(III) complexes incorporating pendent pyridyl groups [J].

Arm, KJ ;

Leslie, W ;

Williams, JAG .

INORGANICA CHIMICA ACTA, 2006, 359 (04) :1222-1232

[3] Structural diversity of building-blocks in coordination framework synthesis -: combining M(NO3)2 junctions and bipyridyl ligands [J].

Barnett, SA ;

Champness, NR .

COORDINATION CHEMISTRY REVIEWS, 2003, 246 (1-2) :145-168

[4]

Batten SR, 1998, ANGEW CHEM INT EDIT, V37, P1460, DOI 10.1002/(SICI)1521-3773(19980619)37:11<1460::AID-ANIE1460>3.0.CO

[5]

2-Z

[6] Topology of interpenetration [J].

Batten, SR .

CRYSTENGCOMM, 2001, (18)

[7] CRYSTALS version 12: software for guided crystal structure analysis [J].

Betteridge, PW ;

Carruthers, JR ;

Cooper, RI ;

Prout, K ;

Watkin, DJ .

JOURNAL OF APPLIED CRYSTALLOGRAPHY, 2003, 36 :1487-1487

[8] Vectorial property dependence in bis{4′-(n-pyridyl)-2,2′:6′,2"-terpyridine}iron(II) and ruthenium(II) complexes with n=2, 3 and 4 [J].

Beves, Jonathon E. ;

Dunphy, Emma L. ;

Constable, Edwin C. ;

Housecroft, Catherine E. ;

Kepert, Cameron J. ;

Neuburger, Markus ;

Price, David J. ;

Schaffner, Silvia .

DALTON TRANSACTIONS, 2008, 3 (03) :386-396

[9] The conjugate acid of bis{4'-(4-pyridyl)-2,2': 6',2"-terpyridine} iron(II) as a self-complementary hydrogen-bonded building block [J].

Beves, Jonathon E. ;

Constable, Edwin C. ;

Housecroft, Catherine E. ;

Kepert, Cameron J. ;

Neuburger, Markus ;

Price, David J. ;

Schaffner, Silvia .

CRYSTENGCOMM, 2007, 9 (11) :1073-1077

[10] The first example of a coordination polymer from the expanded 4,4′-bipyridine ligand [Ru(pytpy)2]2+ (pytpy=4′-(4-pyridyl)2,2′:6′,2"-terpyridine) [J].

Beves, Jonathon E. ;

Constable, Edwin C. ;

Housecroft, Catherine E. ;

Kepert, Cameron J. ;

Price, David J. .

CRYSTENGCOMM, 2007, 9 (06) :456-459

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