The first example of a coordination polymer from the expanded 4,4′-bipyridine ligand [Ru(pytpy)2]2+ (pytpy=4′-(4-pyridyl)2,2′:6′,2"-terpyridine)

被引：79

作者：

Beves, Jonathon E.

Constable, Edwin C.

Housecroft, Catherine E.

Kepert, Cameron J.

Price, David J.

机构：

[1] Univ Basel, Dept Chem, CH-4056 Basel, Switzerland

[2] Univ Sydney, Sch Chem, Sydney, NSW 2006, Australia

来源：

CRYSTENGCOMM | 2007年 / 9卷 / 06期

关键词：

D O I：

10.1039/b703622a

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The complex cation ligand [Ru(pytpy)(2)](2+) ( pytpy = 4'-(4pyridyl)- 2,2':6',2"-terpyridine) is an expanded 4,4'-bipyridine; we describe the first example of a coordination polymer in which [Ru( pytpy)(2)](2+) plays the role of a bridging bidentate ligand.

引用

收藏

页码：456 / 459

页数：4

相关论文

共 28 条

[1] New software for searching the Cambridge Structural Database and visualizing crystal structures [J].

Bruno, IJ ;

Cole, JC ;

Edgington, PR ;

Kessler, M ;

Macrae, CF ;

McCabe, P ;

Pearson, J ;

Taylor, R .

ACTA CRYSTALLOGRAPHICA SECTION B-STRUCTURAL SCIENCE CRYSTAL ENGINEERING AND MATERIALS, 2002, 58 :389-397

[2] Recent advances in supramolecular design and assembly of silver(I) coordination polymers [J].

Chen, CL ;

Kang, BS ;

Su, CY .

AUSTRALIAN JOURNAL OF CHEMISTRY, 2006, 59 (01) :3-18

[3] Self-assembly of a linear multicomponent porphyrin array through axial coordination [J].

Chichak, K ;

Branda, NR .

CHEMICAL COMMUNICATIONS, 1999, (06) :523-524

[4] MULTINUCLEATING 2,2'/6',2''-TERPYRIDINE LIGANDS AS BUILDING-BLOCKS FOR THE ASSEMBLY OF COORDINATION POLYMERS AND OLIGOMERS [J].

CONSTABLE, EC ;

THOMPSON, AMWC .

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1992, (24) :3467-3475

[5] PENDANT-FUNCTIONALIZED LIGANDS FOR METALLOSUPRAMOLECULAR ASSEMBLIES - RUTHENIUM(II) AND OSMIUM(II) COMPLEXES OF 4'-(4-PYRIDYL)-2,2'/6',2''-TERPYRIDINE [J].

CONSTABLE, EC ;

THOMPSON, AMWC .

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1994, (09) :1409-1418

[6]

CONSTABLE EC, 1992, NATO ADV SCI I C-MAT, V371, P219

[7] Metal-directed assembly of a box-like structure [J].

Constable, EC ;

Schofield, E .

CHEMICAL COMMUNICATIONS, 1998, (03) :403-404

[8] Development of supramolecular structure through alkylation of pendant pyridyl functionality [J].

Constable, EC ;

Housecroft, CE ;

Neuburger, M ;

Phillips, D ;

Raithby, PR ;

Schofield, E ;

Sparr, E ;

Tocher, DA ;

Zehnder, M ;

Zimmermann, Y .

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 2000, (13) :2219-2228

[9] LIGAND REACTIVITY IN IRON(II) COMPLEXES OF 4'-(4'''-PYRIDYL)-2,2'/6',2''-TERPYRIDINE [J].

CONSTABLE, EC ;

THOMPSON, AMWC .

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1992, (20) :2947-2950

[10] PH-sensitive Ru(II) and Os(II) bis(2,2′:6′,2"-terpyridine) complexes:: A photophysical investigation [J].

Constable, Edwin C. ;

Housecroft, Catherine E. ;

Thompson, Alexander Cargill ;

Passaniti, Paolo ;

Silvi, Serena ;

Maestri, Mauro ;

Credi, Alberto .

INORGANICA CHIMICA ACTA, 2007, 360 (03) :1102-1110