Ionothermal Synthesis of BiOCl Nanostructures via a Long-Chain Ionic Liquid Precursor Route

被引：121

作者：

Ma, Jianmin ^{[1
]}

Liu, Xiaodi ^{[1
]}

Lian, Jiabiao ^{[1
]}

Duan, Xiaochuan ^{[1
]}

Zheng, Wenjun ^{[1
]}

机构：

[1] Nankai Univ, Coll Chem, Dept Chem Mat, Tianjin 300071, Peoples R China

来源：

CRYSTAL GROWTH & DESIGN | 2010年 / 10卷 / 06期

基金：

中国国家自然科学基金;

关键词：

MICROWAVE-ASSISTED SYNTHESIS; METAL-ORGANIC FRAMEWORKS; PHOTOCATALYTIC ACTIVITY; PHASE-BEHAVIOR; 1-BUTYL-3-METHYLIMIDAZOLIUM TETRAFLUOROBORATE; CRYSTAL-STRUCTURE; WATER; ELECTRODEPOSITION; TEMPLATE; NANOWIRES;

D O I：

10.1021/cg900940s

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Ultrathin BiOCl nanoflakes, nanoplate arrays, and curved nanoplates have been successfully synthesized via an ionothermal synthetic route by using an ionic liquid 1-hexadecyl-3-methylimidazolium chloride ([C(16)Mim]Cl) as "all-in-one" solvent, simply adjusting reaction temperature. The samples are characterized by X-ray diffraction (XRD), scanning electron microscopy (SEM), transmission electron microscopy (TEM), high-resolution transmission electron microscopy (HR-TEM) and Fourier transform infrared spectroscopy (FT-IR), separately. Possible formation mechanisms of various nanostructures were proposed in terms of crystal growth habit and dynamics. In addition, the excellent adsorption performance of the as-prepared BiOCl nanoplates makes them useful with potential applications in the aspect of wastewater treatment.

引用

页码：2522 / 2527

页数：6

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