Selective solution-phase synthesis of BiOCl, BiVO4 and δ-Bi2O3 nanocrystals in the reaction system of BiCl3-NH4VO3-NaOH

被引:31
作者
Chen, Xiang Ying [1 ]
Zhang, Zhong Jie [2 ]
Lee, Soon W. [3 ]
机构
[1] Hefei Univ Technol, Sch Chem Engn, Dept Appl Chem, Hefei 230009, Anhui, Peoples R China
[2] Anhui Univ, Coll Chem & Chem Engn, Dept Chem Engn, Hefei 230039, Anhui, Peoples R China
[3] Sungkyunkwan Univ, Dept Chem BK21, Suwon 440746, South Korea
关键词
solution-phase; bismuth compounds; nanomaterials; photoluminescence;
D O I
10.1016/j.jssc.2007.10.031
中图分类号
O61 [无机化学];
学科分类号
070301 ; 081704 ;
摘要
In this study, we demonstrate a straightforward solution-phase method for the selective synthesis of BiOCl, BiVO4 and delta-Bi2O3 nanocrystals by simply manipulating the reaction temperature and the BiCl3-to-NaOH mole ratio in the reaction system of BiCl3-NH4VO3-NaOH. The experimental results revealed that BiOCl, as the sole product, was prepared when designating the reaction temperature ranging from room temperature to 100 degrees C, regardless of the BiCl3-to-NaOH mole ratio; on the other hand, BiOCl, BiVO4, and delta-Bi2O3 nanocrystals could be selectively prepared at 140-180 degrees C, depending on the BiCl3-to-NaOH mole ratio in solution. Significantly, we first report on fabricating delta-Bi2O3 sample, the high-temperature cubic phase commonly stabilized at 730-824 degrees C, at the low reaction temperature of 140-180 degrees C under solution-phase synthetic conditions. In addition, the delta-Bi2O3 sample exhibits strong emission at room temperature. (c) 2007 Elsevier Inc. All rights reserved.
引用
收藏
页码:166 / 174
页数:9
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