Rydberg electron-transfer spectroscopy and ab initio studies of dimethylsulfoxide-water neutral and anion dimers

被引：17

作者：

Carles, S

Desfrançois, C

Schermann, JP ^{[1
]}

Bergès, J

Houée-Levin, C

机构：

[1] Univ Paris 13, Phys Lasers Lab, F-93430 Villetaneuse, France

[2] Univ Paris 06, Chim Theor Lab, F-75252 Paris, France

[3] Univ Paris 11, LPCR, F-91405 Paris, France

来源：

INTERNATIONAL JOURNAL OF MASS SPECTROMETRY | 2001年 / 205卷 / 1-3期

关键词：

Rydberg electron-transfer spectroscopy;

D O I：

10.1016/S1387-3806(00)00266-9

中图分类号：

O64 [物理化学（理论化学）、化学物理学]; O56 [分子物理学、原子物理学];

学科分类号：

070203 ; 070304 ; 081704 ; 1406 ;

摘要：

Very low energy electron attachment to DMSO and DMSO-water clusters is studied by means of the Rydberg electron-transfer spectroscopy method. Only DMSO- and (DMSO-H2O)(-) anions, with excess electrons in diffuse orbitals, are observed, and the corresponding excess electron-binding energies are, respectively, 12.7 and 3.6 meV. The relative energies and equilibrium geometries of DMSO, DMSO-H2O, and their anions are determined by means of MP2 and DFT calculations and compared to experimental results. (Int J Mass Spectrom 205 (2001) 227-232) (C) 2001 Elsevier Science B.V.

引用

页码：227 / 232

页数：6

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