Zinc-Adeninate Metal-Organic Framework for Aqueous Encapsulation and Sensitization of Near-infrared and Visible Emitting Lanthanide Cations

被引：575

作者：

An, Jihyun ^{[1
]}

Shade, Chad M. ^{[1
]}

Chengelis-Czegan, Demetra A. ^{[1
]}

Petoud, Stephane ^{[1
,2
]}

Rosi, Nathaniel L. ^{[1
]}

机构：

[1] Univ Pittsburgh, Dept Chem, Pittsburgh, PA 15260 USA

[2] CNRS, Ctr Biophys Mol, UPR 4301, F-45071 Orleans, France

来源：

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 2011年 / 133卷 / 05期

基金：

美国国家科学基金会;

关键词：

CO2 ADSORPTION PROPERTIES; YB-III; OXYGEN; COMPLEXES; RECOGNITION; EMISSION; TERBIUM; ANTENNA;

D O I：

10.1021/ja109103t

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Luminescent metal-organic frameworks (MOFs), Ln(3+)@bio-MOF-1, were synthesized via post-synthetic cation exchange of bio-MOF-1 with Tb3+, Sm3+, Eu3+, or Yb3+, and their photophysical properties were studied. We demonstrate that bio-MOF-1 encapsulates and sensitizes visible and near-infrared emitting lanthanide cations in aqueous solution.

引用

页码：1220 / 1223

页数：4