Synthesis and magnetic properties of a metallacryptate that behaves as a single-molecule magnet

被引：116

作者：

Dendrinou-Samara, C

Alexiou, M

Zaleski, CM

Kampf, JW

Kirk, ML

Kessissoglou, DP

Pecoraro, VL

机构：

[1] Univ New Mexico, Dept Chem, Albuquerque, NM 87131 USA

[2] Aristotle Univ Thessaloniki, Dept Gen & Inorgan Chem, Thessaloniki 54124, Greece

[3] Univ Michigan, Dept Chem, Willard H Dow Labs, Ann Arbor, MI 48109 USA

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2003年 / 42卷 / 32期

关键词：

magnetic properties; manganese; metallacycles; metal-metal interactions; single-molecule studies; NETWORK; ANALOG;

D O I：

10.1002/anie.200351246

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Crypt analysis: The reaction of manganese(II) chloride with sodium hydroxide, di-(2-pyridyl)-ketonoxime, and sodium azide yields a metallacryptate consisting of 26 manganese centers, namely, four MnII (see picture; gold spheres) and 22 MnIII ions (green, aqua, and blue spheres). Results obtained from ac SQUID magnetic studies indicate that this molecule displays single-molecule magnetic behavior.

引用

页码：3763 / 3766

页数：4

共 27 条

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