Photoinduced energy transfer in composites of poly[(p-phenylene-1,2-vinylene)-co-(p-phenylene-1,1-vinylidene)] and single-walled carbon nanotubes

被引：25

作者：

Umeyama, Tomokazu ^{[1
]}

Kadota, Naoki ^{[1
]}

Tezuka, Noriyasu ^{[1
]}

Matano, Yoshihiro ^{[1
]}

Imahori, Hiroshi ^{[1
]}

机构：

[1] Kyoto Univ, Grad Sch Engn, Dept Mol Engn, Nishikyo Ku, Kyoto 6158510, Japan

来源：

CHEMICAL PHYSICS LETTERS | 2007年 / 444卷 / 4-6期

关键词：

D O I：

10.1016/j.cplett.2007.07.013

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

A conjugated polymer, poly[(p-phenylene-1,2-vinylene)-co-(p-phenylene-1,1-vinylidene)] (coPPV), with the structural defect caused by 1,1-vinylidene moieties in the main chain of all-trans phenylene-1,2-vinylenes, has been prepared to examine interactions with single-walled carbon nanotubes (SWNTs) in organic solvents. UV-vis-NIR absorption and AFM measurements revealed that SWNTs are dispersed well in organic solvents by pi-pi interaction with coPPV. The composite solution of coPPV SWNTs exhibited a remarkable enhancement of the NIR emission of SWNT with the excitation of coPPV at 400-500 nm, demonstrating the occurrence of energy transfer from the excited coPPV to SWNTs in the composite. (C) 2007 Elsevier B.V. All rights reserved.

引用

页码：263 / 267

页数：5

共 32 条

[21] Fundamental electronic properties and applications of single-walled carbon nanotubes [J].