Asymmetric oxidation with furylhydroperoxides

被引:24
作者
Scettri, A [1 ]
Bonadies, F [1 ]
Lattanzi, A [1 ]
机构
[1] UNIV ROMA LA SAPIENZA,DIPARTIMENTO CHIM,CTR STUDIO CNR CHIM SOSTANZE ORGAN NAT,I-00185 ROME,ITALY
关键词
D O I
10.1016/0957-4166(96)00050-X
中图分类号
O61 [无机化学];
学科分类号
070301 ; 081704 ;
摘要
Chiral sulfoxides are accessible with very satisfactory enantiomeric excesses through a modified Sharpless procedure, based on the employment of furylhydroperoxides. Racemic hydroperoxides are found to undergo a kinetic resolution in the course of the asymmetric oxidation. (C) 1996 Elsevier Science Ltd
引用
收藏
页码:629 / 632
页数:4
相关论文
共 11 条
  • [11] ZAO SH, 1987, TETRAHEDRON, V43, P5135