Dip-pen nanolithography of nanostructured oligofluorene truxenes in a photo-curable host matrix

被引:10
作者
Hernandez-Santana, Aaron [1 ]
Mackintosh, Allan R.
Guilhabert, Benoit [2 ]
Kanibolotsky, Alexander L.
Dawson, Martin D. [2 ]
Skabara, Peter J.
Graham, Duncan [1 ]
机构
[1] Univ Strathclyde, Dept Pure & Appl Chem, WestCHEM, Ctr Mol Nanometrol, Glasgow G1 1XL, Lanark, Scotland
[2] Univ Strathclyde, Inst Photon, Glasgow G4 0NW, Lanark, Scotland
基金
英国工程与自然科学研究理事会;
关键词
INK; MODEL;
D O I
10.1039/c1jm11378j
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
We report the controlled patterning of nano-sized oligofluorene truxenes onto silicon dioxide by dip-pen nanolithography (DPN) using a UV-curable pre-polymer as a carrier fluid. In this technique, a sharp atomic force microscope (AFM) cantilever tip is used to transfer the liquid ink onto a surface using piezo-controlled movements and excellent spatial registry. The photo-curable carrier fluid is then exposed to UV-light to produce a cross-linked, host matrix while retaining the photoluminescent properties of the truxenes and providing protection against photo-oxidation. The chemical composition of the composite structures deposited by DPN was characterised by Raman microspectroscopy and microphotoluminescence to demonstrate successful incorporation of the photoluminescent truxenes in the polymer matrix.
引用
收藏
页码:14209 / 14212
页数:4
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