Thermal decomposition as route for silver nanoparticles

被引:211
作者
Navaladian, S. [1 ]
Viswanathan, B. [1 ]
Viswanath, R. P. [1 ]
Varadarajan, T. K. [1 ]
机构
[1] Indian Inst Technol, Dept Chem, Natl Ctr Catalysis Res, Madras 600036, Tamil Nadu, India
来源
NANOSCALE RESEARCH LETTERS | 2007年 / 2卷 / 01期
关键词
Ag nanoparticles; synthesis; silver oxalate; thermal decomposition; E; coli;
D O I
10.1007/s11671-006-9028-2
中图分类号
TB3 [工程材料学];
学科分类号
0805 ; 080502 ;
摘要
Single crystalline silver nanoparticles have been synthesized by thermal decomposition of silver oxalate in water and in ethylene glycol. Polyvinyl alcohol (PVA) was employed as a capping agent. The particles were spherical in shape with size below 10 nm. The chemical reduction of silver oxalate by PVA was also observed. Increase of the polymer concentration led to a decrease in the size of Ag particles. Ag nanoparticle was not formed in the absence of PVA. Antibacterial activity of the Ag colloid was studied by disc diffusion method.
引用
收藏
页码:44 / 48
页数:5
相关论文
共 17 条
[1]   A SERS-active system based on silver nanoparticles tethered to a deposited silver film [J].
Anderson, D. J. ;
Moskovits, M. .
JOURNAL OF PHYSICAL CHEMISTRY B, 2006, 110 (28) :13722-13727
[2]   Thermal decomposition of silver oxalate [J].
Boldyrev, VV .
THERMOCHIMICA ACTA, 2002, 388 (1-2) :63-90
[3]  
Elechiguerra Jose Luis, 2005, J Nanobiotechnology, V3, P6
[4]  
Forster S, 1998, ADV MATER, V10, P195, DOI 10.1002/(SICI)1521-4095(199802)10:3<195::AID-ADMA195>3.0.CO
[5]  
2-V
[6]   KINETICS OF REDUCTION OF IODINE BY OXALATE AND FORMATE IONS IN AN AQUEOUS-SOLUTION - DIFFERENCE IN MECHANISMS OF THE REACTIONS OF OXALATE AND FORMATE IONS WITH IODINE [J].
KIMURA, M ;
ISHIGURO, H ;
TSUKAHARA, K .
JOURNAL OF PHYSICAL CHEMISTRY, 1990, 94 (10) :4106-4110
[7]   Synthesis of silver nanocrystallites by a new thermal decomposition method and their characterization [J].
Lee, DK ;
Kang, YS .
ETRI JOURNAL, 2004, 26 (03) :252-256
[8]  
LEIGA AG, 1996, J PHYS CHEM, V70, P3260
[9]  
Milazzo G., 1978, TABLES STANDARD ELEC
[10]   The role of 'ideal' and 'real' crystal structure in the solid-state decomposition of silver oxalate: Experimental diffraction studies and theoretical calculations [J].
Naumov, DY ;
Boldyreva, EV ;
Podberezskaya, NV ;
Howard, JAK .
SOLID STATE IONICS, 1997, 101 :1315-1320