Syntheses, characterization and photochemical properties of new NO•-ruthenium(II) complexes

被引：28

作者：

Sauaia, MG

Oliveira, FDS

de Lima, RG

Cacciari, ADL

Tfouni, E

da Silva, RS

机构：

[1] Univ Sao Paulo, Fac Filosofia Ciencias & Letras Ribeirao Pret, Dept Quim, BR-14040901 Ribeirao Preto, SP, Brazil

[2] Univ Sao Paulo, Fac Ciencias Farmaceut Ribeirao Preto, BR-14040903 Ribeirao Preto, SP, Brazil

来源：

INORGANIC CHEMISTRY COMMUNICATIONS | 2005年 / 8卷 / 04期

基金：

巴西圣保罗研究基金会;

关键词：

nitric oxide; ruthenium complexes; nitrosyl ruthenium complexes;

D O I：

10.1016/j.inoche.2005.01.012

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The synthesis, chemical and photochemical properties of cis-[Ru-II(bpy)(2)L(NO0)](PF6)(2) (L = pyridine, 4-picoline or 4-acetylpyridine) in physiological solution are reported. The photolysis in the visible region of cis-[Ru-II(bpy)(2)(4-pic)(NO0)](2+) produces nitric oxide and cis-[Ru-II(bpy)(2)(4-pic)(H2O)](2+), suggesting the possibility to use such nitrosyl ruthenium complexes photochemically in therapy. (c) 2005 Elsevier B.V. All rights reserved.

引用

页码：347 / 349

页数：3

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