Control of Interpenetration for Tuning Structural Flexibility Influences Sorption Properties

被引：189

作者：

Bureekaew, Sareeya ^{[1
]}

Sato, Hiroshi ^{[1
]}

Matsuda, Ryotaro ^{[1
,2
,5
]}

Kubota, Yoshiki ^{[3
,5
]}

Hirose, Raita ^{[1
]}

Kim, Jungeun ^{[4
]}

Kato, Kenichi ^{[5
]}

Takata, Masaki ^{[4
,5
]}

Kitagawa, Susumu ^{[1
,2
,5
]}

机构：

[1] Japan Sci & Technol Agcy, ERATO Kitagawa Integrated Pores Project, Shimogyo Ku, Kyoto 6008815, Japan

[2] Kyoto Univ, Inst Integrated Cell Mat Sci, Kyoto 6158510, Japan

[3] Osaka Prefecture Univ, Grad Sch Sci, Dept Phys Sci, Osaka 5998531, Japan

[4] Japan Synchrotron Radiat Res Inst, Hyogo 6795198, Japan

[5] RIKEN, Mikazuki, Hyogo 6795148, Japan

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2010年 / 49卷 / 42期

关键词：

carbon dioxide; coordination polymers; host-guest systems; hybrid materials; phase transitions; METAL-ORGANIC FRAMEWORK; POROUS COORDINATION-POLYMER; CATENATION ISOMERISM; HYDROGEN STORAGE; ADSORPTION; CATALYSIS; DESIGN; CHIRALITY; NETWORKS; CHANNELS;

D O I：

10.1002/anie.201002259

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Transforming jungle gyms: Structural flexibility and sorption behavior can be tuned by controlling the degree of interpenetration of 3D porous coordination polymers (PCPs). The architectural connectivity of PCPs, even those that are composed of the same chemical components, has a significant impact on the structural flexibility and sorption behavior, which was confirmed by coincident XRPD/adsorption measurements. © 2010 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim.

引用

页码：7660 / 7664

页数：5

共 61 条

[1]

[Anonymous], 2004, ANGEW CHEM INT EDIT, DOI DOI 10.1002/ANGE.200460712

[2]

[Anonymous], 2006, ANGEW CHEM, DOI DOI 10.1002/ANGE.200503503

[3] Interpenetrating metal-organic and inorganic 3D networks: a computer-aided systematic investigation. Part II. Analysis of the Inorganic Crystal Structure Database (ICSD) [J].

Baburin, IA ;

Blatov, VA ;

Carlucci, L ;

Ciani, G ;

Proserpio, DM .

JOURNAL OF SOLID STATE CHEMISTRY, 2005, 178 (08) :2452-2474

[4] On the mechanism of hydrogen storage in a metal-organic framework material [J].

Belof, Jonathan L. ;

Stern, Abraham C. ;

Eddaoudi, Mohamed ;

Space, Brian .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2007, 129 (49) :15202-15210

[5] Oriented growth of the metal organic framework Cu3(BTC)2(H2O)3•xH2O tunable with functionalized self-assembled monolayers [J].

Biemmi, Enrica ;

Scherb, Camilla ;

Bein, Thomas .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2007, 129 (26) :8054-+

[6] Interpenetrating metal-organic and inorganic 3D networks: a computer-aided systematic investigation. Part I. Analysis of the Cambridge structural database [J].

Blatov, VA ;

Carlucci, L ;

Ciani, G ;

Proserpio, DM .

CRYSTENGCOMM, 2004, 6 :377-395

[7] Design, chirality, and flexibility in nanoporous molecule-based materials [J].

Bradshaw, D ;

Claridge, JB ;

Cussen, EJ ;

Prior, TJ ;

Rosseinsky, MJ .

ACCOUNTS OF CHEMICAL RESEARCH, 2005, 38 (04) :273-282

[8]

Bradshaw D, 2007, SCIENCE, V315, P977, DOI [10.1126/science.1135445, 10.1126/science1135445]

[9]

Braga D., 2007, MAKING CRYSTALS DESI

[10] A route to high surface area, porosity and inclusion of large molecules in crystals [J].

Chae, HK ;

Siberio-Pérez, DY ;

Kim, J ;

Go, Y ;

Eddaoudi, M ;

Matzger, AJ ;

O'Keeffe, M ;

Yaghi, OM .

NATURE, 2004, 427 (6974) :523-527

← 1 2 3 4 5 6 7 →