Synthesis of B2,5 type conformationally constrained glucopyranosides

被引：15

作者：

Blériot, Y

Vadivel, SK

Greig, IR

Kirby, AJ ^{[1
]}

Sinay, P

机构：

[1] Univ Cambridge, Chem Lab, Cambridge CB2 1EW, England

[2] Ecole Normale Super, UMR CNRS 8642, Dept Chim, F-75231 Paris 05, France

来源：

TETRAHEDRON LETTERS | 2003年 / 44卷 / 35期

关键词：

carbohydrates; conformation; hydrolysis;

D O I：

10.1016/S0040-4039(03)01631-9

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Isopropyl and p-nitrophenyl alpha- and beta-D-glucopyranosides restrained in a conformation close to B-2,B-5 have been synthesized. They are all hydrolyzed at similar rates, close to those observed for the parent unlocked glucosides. (C) 2003 Elsevier Ltd. All rights reserved.

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收藏

页码：6687 / 6690

页数：4

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