Synthesis and characterization of bis(2-aminophenyl)disulphide diimine derivatives and their ruthenium complexes

被引：11

作者：

Bhowon, MG ^{[1
]}

Jhaumeer-Laulloo, S ^{[1
]}

Dowlut, M ^{[1
]}

Curpen, S ^{[1
]}

Jumnoodoo, V ^{[1
]}

机构：

[1] Univ Mauritius, Fac Sci, Dept Chem, Reduit, Mauritius

来源：

TRANSITION METAL CHEMISTRY | 2005年 / 30卷 / 01期

关键词：

D O I：

10.1007/s11243-004-3669-8

中图分类号：

O61 [无机化学];

学科分类号：

070301 [无机化学]; 081704 [应用化学];

摘要：

Condensation of bis(2-aminophenyl) disulphide with aromatic aldehydes yielded the corresponding dithiophenyldiimines. Dinuclear ruthenium complexes were obtained by reacting the diimines ( 3) [bis(3-nitrobenzaldehyde)- phenyldisulphide diimine], (5) [ bis(2-chlorobenzaldehyde)-phenyldisulphide diimine], (8) [bis(2-methoxybenzaldehyde)-phenyldisulphide diimine] and (9) [bis(2-hydroxybenzaldehyde)-phenyldisulphide diimine], with RuCl3 in the presence of L ( L = 2,2'-bipyridine, 1,10-phenanthroline, 3,4-diaminotoluene, pyridine and PPh3) in EtOH. The two metal centres, connected through bridging chlorides, are in octahedral environments with one metal centre coordinated to sulphur and water while the other is coordinated to L.

引用

页码：35 / 39

页数：5

共 14 条

[1]

Abrams M. J., 1995, PLATIN MET REV, V39, P14

[2]

SYNTHESIS AND CHARACTERIZATION OF SOME NEW NICKEL(II), ZINC(II) AND CADMIUM(II) COMPLEXES OF QUADRIDENTATE SNNS LIGANDS [J].