An improved procedure for the epoxidation of methyl cinnamate derivatives and production of acid sensitive epoxides

被引：14

作者：

Moyna, G ^{[1
]}

Williams, HJ ^{[1
]}

Scott, AI ^{[1
]}

机构：

[1] TEXAS A&M UNIV,DEPT CHEM,CTR BIOL NMR,COLLEGE STN,TX 77843

来源：

SYNTHETIC COMMUNICATIONS | 1996年 / 26卷 / 11期

基金：

美国国家卫生研究院;

关键词：

D O I：

10.1080/00397919608003584

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

By using a biphasic epoxidation system, unreactive methyl cinnamate derivatives were epoxidized at higher rates, and epoxides that decomposed in the presence of m-chlorobenzoic acid (mCBA) to diol ester opening products under standard conditions were obtained in fair to excellent yields.

引用

页码：2235 / 2239

页数：5