An improved procedure for the epoxidation of methyl cinnamate derivatives and production of acid sensitive epoxides

被引:14
作者
Moyna, G [1 ]
Williams, HJ [1 ]
Scott, AI [1 ]
机构
[1] TEXAS A&M UNIV,DEPT CHEM,CTR BIOL NMR,COLLEGE STN,TX 77843
基金
美国国家卫生研究院;
关键词
D O I
10.1080/00397919608003584
中图分类号
O62 [有机化学];
学科分类号
070303 ; 081704 ;
摘要
By using a biphasic epoxidation system, unreactive methyl cinnamate derivatives were epoxidized at higher rates, and epoxides that decomposed in the presence of m-chlorobenzoic acid (mCBA) to diol ester opening products under standard conditions were obtained in fair to excellent yields.
引用
收藏
页码:2235 / 2239
页数:5
相关论文
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[11]  
1963, ORG REACTIONS, V1, P210