One-step synthesis of phenol by O- and OH- emission material

被引：70

作者：

Dong, T

Li, J

Huang, F

Wang, L

Tu, J

Torimoto, Y

Sadakata, M

Li, QX ^{[1
]}

机构：

[1] Univ Sci & Technol China, Dept Phys Chem, BCL Lab, Hefei 230026, Anhui, Peoples R China

[2] Univ Tokyo, Sch English, Dept Chem Syst Engn, Bunkyo Ku, Tokyo 1138656, Japan

来源：

CHEMICAL COMMUNICATIONS | 2005年 / 21期

关键词：

D O I：

10.1039/b419206k

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A novel approach to the direct synthesis of phenol from benzene was obtained with high benzene conversion (30%) and phenol selectivity (similar to 90%) by using a microporous material [Ca24Al28O64](4+)center dot 4O(-) ( C12A7-O-) as catalyst with oxygen and water; active O- and OH- anions are proposed to play important roles in the formation of phenol by hydroxylating the aromatic ring of benzene.

引用

页码：2724 / 2726

页数：3

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