Double yielding behaviors of polyamide 6 and glass bead filled polyamide 6 composites

被引:39
作者
Shan, GF [1 ]
Yang, W [1 ]
Xie, BH [1 ]
Li, ZM [1 ]
Chen, J [1 ]
Yang, MB [1 ]
机构
[1] Sichuan Univ, Coll Polymer Sci & Engn, State Key Lab Polymer Mat Engn, Chengdu 610065, Sichuan, Peoples R China
基金
高等学校博士学科点专项科研基金; 中国国家自然科学基金;
关键词
polyamide; 6; glass bead; deformation behavior; double yielding;
D O I
10.1016/j.polymertesting.2005.05.003
中图分类号
TB3 [工程材料学];
学科分类号
0805 ; 080502 ;
摘要
Double yield points before necking were observed in injection molded specimens of polyamide 6 (PA6) and PA6/glass bead (GB) composites under tensile loading. The results indicated that the unusual phenomenon was in correlation with the tensile velocity, the composition of the composites and the crystallinity of the matrix at different stages in the course of the tensile test. With higher tensile velocity, addition of glass beads and bead content increasing, the phenomenon of double yielding was depressed. Differential scanning calorimetry (DSC) and X-ray diffraction (XRD) studies indicated that the double yielding was only present in samples with less than 50% crystallinity and the crystalline structure and the size of crystallite of the samples in different tensile stages were also changed. (c) 2005 Elsevier Ltd. All rights reserved.
引用
收藏
页码:704 / 711
页数:8
相关论文
共 26 条
[1]   Double yielding in a styrene/butadiene star block copolymer [J].
Adhikari, R ;
Buschnakowski, M ;
Henning, S ;
Goerlitz, S ;
Huy, TA ;
Lebek, W ;
Godehardt, R ;
Michler, GH ;
Lach, R ;
Geiger, K ;
Kno, K .
MACROMOLECULAR RAPID COMMUNICATIONS, 2004, 25 (05) :653-658
[2]   CRYSTAL STRUCTURE OF GAMMA-FORM OF NYLON 6 [J].
ARIMOTO, H ;
ISHIBASH.M ;
HIRAI, M ;
CHATANI, Y .
JOURNAL OF POLYMER SCIENCE PART A-GENERAL PAPERS, 1965, 3 (1PA) :317-&
[3]   THE PHENOMENON OF DOUBLE YIELDING UNDER TENSION IN LOW-DENSITY POLYETHYLENE, LINEAR LOW-DENSITY POLYETHYLENE AND THEIR BLENDS [J].
BALSAMO, V ;
MULLER, AJ .
JOURNAL OF MATERIALS SCIENCE LETTERS, 1993, 12 (18) :1457-1459
[4]   INVESTIGATION INTO DOUBLE YIELD POINTS IN POLYETHYLENE [J].
BROOKS, NW ;
DUCKETT, RA ;
WARD, IM .
POLYMER, 1992, 33 (09) :1872-1880
[5]   DOUBLE YIELD POINTS IN POLYETHYLENE - STRUCTURAL-CHANGES UNDER TENSILE DEFORMATION [J].
BROOKS, NWJ ;
UNWIN, AP ;
DUCKETT, RA ;
WARD, IM .
JOURNAL OF MACROMOLECULAR SCIENCE-PHYSICS, 1995, B34 (1-2) :29-54
[6]   MODELING OF DOUBLE YIELD POINTS IN POLYETHYLENE - TEMPERATURE AND STRAIN-RATE DEPENDENCE [J].
BROOKS, NWJ ;
DUCKETT, RA ;
WARD, IM .
JOURNAL OF RHEOLOGY, 1995, 39 (02) :425-436
[7]   Structure and thermal properties of blends of nylon 6 and a liquid crystal copolyester [J].
Campoy, I ;
Gomez, MA ;
Marco, C .
POLYMER, 1998, 39 (25) :6279-6288
[8]   The phenomenon of double yielding in oriented high density polyethylene films [J].
Feijoo, JL ;
Sanchez, JJ ;
Muller, AJ .
JOURNAL OF MATERIALS SCIENCE LETTERS, 1997, 16 (21) :1721-1724
[9]   MOLECULAR MORPHOLOGY IN SEMI-CRYSTALLINE POLYMERS [J].
FLORY, PJ ;
YOON, DY .
NATURE, 1978, 272 (5650) :226-229
[10]   Crystallization behavior of nylon 6 nanocomposites [J].
Fornes, TD ;
Paul, DR .
POLYMER, 2003, 44 (14) :3945-3961