Reactivity of Lewis pairs (R2PCH2AlMe2)2 with carbon dioxide

被引：123

作者：

Boudreau, Josee

Courtemanche, Marc-Andre

Fontaine, Frederic-Georges ^{[1
]}

机构：

[1] Univ Laval, Dept Chim, Quebec City, PQ G1K 7P4, Canada

来源：

CHEMICAL COMMUNICATIONS | 2011年 / 47卷 / 39期

关键词：

FREE HYDROGEN ACTIVATION; STRUCTURAL-CHARACTERIZATION; AMMONIA BORANE; CO2; COORDINATION; COMPLEXES; MECHANISM; BINDING; LIGAND;

D O I：

10.1039/c1cc14641f

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Species R2PCH2AlMe2 (R = Me, Ph) are stable Lewis adducts but still react with CO2 both in solution and in the solid state. The CO2 adducts undergo a rearrangement unprecedented for ambiphilic molecules to form aluminium carboxylates. A new spirocyclic compound was also obtained by double Lewis pair activation of CO2.

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页码：11131 / 11133

页数：3

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