Unexpected appearance of molecular ferromagnetism in the ordinary acetate [{Gd(OAc)3(H2O)2}2]•4H2O

被引：113

作者：

Hatscher, ST ^{[1
]}

Urland, W ^{[1
]}

机构：

[1] Leibniz Univ Hannover, Inst Anorgan Chem, D-30167 Hannover, Germany

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2003年 / 42卷 / 25期

关键词：

carboxylate ligands; gadolinium; lanthanides; magnetic properties;

D O I：

10.1002/anie.200250738

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Breaking the law: Whereas antiferromagnetic interactions in crystalline carboxylates of lanthanides are often observed, ferromagnetism is unknown. The first example of a ferromagnetic interaction is observed for a crystalline sample of the gadolinium compound [{Gd(OAc)3(H2O)2}2]· 4H2O (see picture Gd: gray, O: red).

引用

页码：2862 / 2864

页数：3

共 31 条

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