Synthesis of fluoroalkyl-derivatised BINAP ligands

被引:49
作者
Birdsall, DJ
Hope, EG
Stuart, AM [1 ]
Chen, WP
Hu, YL
Xiao, JL
机构
[1] Univ Leicester, Dept Chem, Leicester LE1 7RH, Leics, England
[2] Univ Liverpool, Dept Chem, Leverhulme Ctr Innovat Catalysis, Liverpool L69 7ZD, Merseyside, England
基金
英国工程与自然科学研究理事会;
关键词
asymmetric hydrogenation; fluorous ponytails; ruthenium catalysts;
D O I
10.1016/S0040-4039(01)01835-4
中图分类号
O62 [有机化学];
学科分类号
070303 ; 081704 ;
摘要
Fluoroalkyl-derivatised R-BINAP ligands have been prepared, characterised and applied in the ruthenium-catalysed asymmetric hydrogenation of dimethyl itaconate, (C) 2001 Elsevier Science Ltd. All rights reserved.
引用
收藏
页码:8551 / 8553
页数:3
相关论文
共 26 条
  • [1] Alvey LJ, 2000, EUR J INORG CHEM, P1975
  • [2] Barthel-Rosa LP, 1999, COORDIN CHEM REV, V190, P587
  • [3] Phosphorus(III) ligands with fluorous ponytails
    Bhattacharyya, P
    Gudmunsen, D
    Hope, EG
    Kemmitt, RDW
    Paige, DR
    Stuart, AM
    [J]. JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 1, 1997, (24): : 3609 - 3612
  • [4] SYNTHESIS OF CHIRAL 2,2'-BIS(DIPHENYLPHOSPHINO)-1,1'-BINAPHTHYL (BINAP) VIA A NOVEL NICKEL-CATALYZED PHOSPHINE INSERTION
    CAI, DW
    PAYACK, JF
    BENDER, DR
    HUGHES, DL
    VERHOEVEN, TR
    REIDER, PJ
    [J]. JOURNAL OF ORGANIC CHEMISTRY, 1994, 59 (23) : 7180 - 7181
  • [5] Second-generation fluorous chiral (salen) manganese complexes
    Cavazzini, M
    Manfredi, A
    Montanari, F
    Quici, S
    Pozzi, G
    [J]. CHEMICAL COMMUNICATIONS, 2000, (21) : 2171 - 2172
  • [6] Palladium-catalyzed synthesis of aqueous, fluorous, and supercritical CO2-soluble phosphines
    Chen, WP
    Xu, LJ
    Xiao, JL
    [J]. ORGANIC LETTERS, 2000, 2 (17) : 2675 - 2677
  • [7] A general method to fluorous ponytail-substituted aromatics
    Chen, WP
    Xu, LJ
    Xiao, JL
    [J]. TETRAHEDRON LETTERS, 2001, 42 (25) : 4275 - 4278
  • [8] Novel and efficient synthesis of perfluoroalkylated arylphosphines
    Chen, WP
    Xiao, JL
    [J]. TETRAHEDRON LETTERS, 2000, 41 (19) : 3697 - 3700
  • [9] Fluorous phase separation techniques in catalysis
    de Wolf, E
    van Koten, G
    Deelman, BJ
    [J]. CHEMICAL SOCIETY REVIEWS, 1999, 28 (01) : 37 - 41
  • [10] Fish RH, 1999, CHEM-EUR J, V5, P1677, DOI 10.1002/(SICI)1521-3765(19990604)5:6<1677::AID-CHEM1677>3.3.CO