Amine-Functionalized MIL-53 Metal-Organic Framework in Polyimide Mixed Matrix Membranes for CO2/CH4 Separation

被引：182

作者：

Chen, Xiao Yuan ^{[1
]}

Vinh-Thang, Hoang ^{[1
]}

Rodrigue, Denis ^{[1
]}

Kaliaguine, Serge ^{[1
]}

机构：

[1] Univ Laval, Dept Chem Engn, Quebec City, PQ G1V 0A6, Canada

来源：

INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH | 2012年 / 51卷 / 19期

基金：

加拿大自然科学与工程研究理事会;

关键词：

6FDA-ODA COPOLYIMIDE MEMBRANES; GAS-SEPARATION; CROSS-LINKING; INTRINSIC MICROPOROSITY; POLYMERS; PERFORMANCE; TRANSPORT; SOLIDS; CO2; PERVAPORATION;

D O I：

10.1021/ie3004336

中图分类号：

TQ [化学工业];

学科分类号：

0817 ;

摘要：

Flexible crystalline metal-organic framework (MOF) of nanosize particles (Al-MIL-53) and 6FDA-ODA polyimides were used to produce mixed matrix membranes (MMM). These MMM display excellent CO2/CH4 separation properties even without any compatibilization (amine grafting). The ideal selectivity and separation factor were found to increase with increasing MOF loading. Furthermore, these materials have an improved CO2/CH4 separation factor with increasing pressure, in contrast to traditional polymer membranes.

引用

页码：6895 / 6906

页数：12

共 71 条

[31]

Liu C., 2008, ADV MEMBRANE TECHNOL, P789

[32]

Liu C, 2009, United States patent US, Patent No. [7,637,983, 7637983]

[33] Chemical cross-linking modification of polyimide membranes for gas separation [J].

Liu, Y ;

Wang, R ;

Chung, TS .

JOURNAL OF MEMBRANE SCIENCE, 2001, 189 (02) :231-239

[34] A rationale for the large breathing of the porous aluminum terephthalate (MIL-53) upon hydration [J].

Loiseau, T ;

Serre, C ;

Huguenard, C ;

Fink, G ;

Taulelle, F ;

Henry, M ;

Bataille, T ;

Férey, G .

CHEMISTRY-A EUROPEAN JOURNAL, 2004, 10 (06) :1373-1382

[35]

Mahajan R, 2002, POLYM ENG SCI, V42, P1420, DOI 10.1002/pen.11041

[36] Tuning functional sites and thermal stability of mixed-linker MOFs based on MIL-53(Al) [J].

Marx, Stefan ;

Kleist, Wolfgang ;

Huang, Jun ;

Maciejewski, Marek ;

Baiker, Alfons .

DALTON TRANSACTIONS, 2010, 39 (16) :3795-3798

[37] Polymers of intrinsic microporosity (PIMs): organic materials for membrane separations, heterogeneous catalysis and hydrogen storage [J].

McKeown, Neil B. ;

Budd, Peter M. .

CHEMICAL SOCIETY REVIEWS, 2006, 35 (08) :675-683

[38] Exploitation of Intrinsic Microporosity in Polymer-Based Materials [J].

McKeown, Neil B. ;

Budd, Peter M. .

MACROMOLECULES, 2010, 43 (12) :5163-5176

[39]

Musselman Jr I. H., 2008, DEFG2604NT42173 U TE

[40] Dynamic Mechanical Analysis of Ethylene-Propylene-Diene Monomer Rubber and Styrene-Butadiene Rubber Blends [J].

Nair, T. Muraleedharan ;

Kumaran, M. G. ;

Unnikrishnan, G. ;

Piiai, V. B. .

JOURNAL OF APPLIED POLYMER SCIENCE, 2009, 112 (01) :72-81

← 1 2 3 4 5 6 7 8 →