Towards the Isomer-Specific Synthesis of Higher Fullerenes and Buckybowls by the Surface-Catalyzed Cyclodehydrogenation of Aromatic Precursors

被引：60

作者：

Amsharov, Konstantin ^{[1
]}

Abdurakhmanova, Nasiba ^{[1
]}

Stepanow, Sebastian ^{[1
]}

Rauschenbach, Stephan ^{[1
]}

Jansen, Martin ^{[1
]}

Kern, Klaus ^{[1
,2
]}

机构：

[1] Max Planck Inst Festkorperforsch, Heisenbergstr 1, D-70569 Stuttgart, Germany

[2] Ecole Polytech Fed Lausanne, Inst Phys Matiere Condensee, CH-1015 Lausanne, Switzerland

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2010年 / 49卷 / 49期

关键词：

cyclodehydrogenation; fullerenes; heterogeneous catalysis; nanotechnology; surface chemistry; CHEMICAL-SYNTHESIS; C-60; TRANSITION;

D O I：

10.1002/anie.201005000

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Fullerenes on a plate: A surface-catalyzed cyclodehydrogenation reaction enabled selective fullerene-cage formation from polycyclic organic precursors. As no C-C bond rearrangement occurred during the reaction, only specifically designed precursors gave the desired fullerene (see picture). This efficient and selective condensation process opens new horizons in the directed synthesis of fullerenes and related structures. Copyright © 2010 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

引用

页码：9392 / 9396

页数：5

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