The formaldehyde sensitivity of LaFe1-xZnxO3-based gas sensor

被引:45
作者
Huang, Shanxing
Qin, Hongwei [1 ]
Song, Peng
Liu, Xing
Li, Lun
Zhang, Rui
Hu, Jifan
Yan, Hongdan
Jiang, Minhua
机构
[1] Shandong Univ, State Key Lab Crystal Mat, Jinan 250100, Peoples R China
[2] Shandong Univ, Dept Phys, Jinan 250100, Peoples R China
[3] Kunming Univ Sci & Technol, Dept Phys, Kunming, Peoples R China
基金
中国国家自然科学基金;
关键词
D O I
10.1007/s10853-007-1991-1
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
Rare earth oxides LaFe1-x Zn (x) O-3 were synthesized by sol-gel method. The X-ray diffraction patterns (XRD) showed that LaFe1-x Zn (x) O(3)oxides are single phase with orthorhombic perovskite structure, they all show p-type semiconducting properties. Among nanocrystalline LaFe1-x Zn (x) O-3 oxides, LaFe0.77Zn0.23O3 exhibits the highest sensitivity of 44.5 to 100 ppm formaldehyde. The optimal working temperature was found to be around 240 degrees C. Moreover the LaFe0.77Zn0.23O3 exhibites short response and recovery time to 100 ppm formaldehyde. The lattice parameter doesn't agree with Vegard's law with the increasing Zn content, and the relative density was 70-80%.
引用
收藏
页码:9973 / 9977
页数:5
相关论文
共 18 条
[1]   Crystallographic characterization and NO2 gas sensing property of LnFeO3 prepared by thermal decomposition of Ln-Fe hexacyanocomplexes, Ln[Fe(CN)6]•nH2O, Ln = La, Nd, Sm, Gd, and Dy [J].
Aono, H ;
Traversa, E ;
Sakamoto, M ;
Sadaoka, Y .
SENSORS AND ACTUATORS B-CHEMICAL, 2003, 94 (02) :132-139
[2]   Synthesis of La0.8Sr0.2Co0.5Ni0.5O3-δ thin films for high sensitivity CO sensing material using the Pechini process [J].
Chai, YL ;
Ray, DT ;
Chen, GJ ;
Chang, YH .
JOURNAL OF ALLOYS AND COMPOUNDS, 2002, 333 (1-2) :147-153
[3]   The influence of microstructure and deposition methods on CO gas sensing properties of La0.8Sr0.2Co1-xNixO3-δ perovskite films [J].
Chiu, CM ;
Chang, YH .
SENSORS AND ACTUATORS B-CHEMICAL, 1999, 54 (03) :236-242
[4]   The structure, electrical and sensing properties for CO of the La0.8Sr0.2Co1-xNixO3-δ system [J].
Chiu, CM ;
Chang, YH .
MATERIALS SCIENCE AND ENGINEERING A-STRUCTURAL MATERIALS PROPERTIES MICROSTRUCTURE AND PROCESSING, 1999, 266 (1-2) :93-98
[5]   Characteristics and sensing properties of dipped La0.8Sr0.2Co1-xNixO3-δ film for CO gas sensors [J].
Chiu, CM ;
Chang, YH .
THIN SOLID FILMS, 1999, 342 (1-2) :15-19
[6]   Effect of formaldehyde on the expression of adhesion molecules in nasal microvascular endothelial cells: the role of formaldehyde in the pathogenesis of sick building syndrome [J].
Kim, WJ ;
Terada, N ;
Nomura, T ;
Takahashi, R ;
Lee, SD ;
Park, JH ;
Konno, A .
CLINICAL AND EXPERIMENTAL ALLERGY, 2002, 32 (02) :287-295
[7]  
KIVEER PS, 1978, PHYS SEMICONDUCTOR, V1, P32
[8]   Gas-sensing property and mechanism of CaxLa1-xFeO3 ceramics [J].
Kong, LB ;
Shen, YS .
SENSORS AND ACTUATORS B-CHEMICAL, 1996, 30 (03) :217-221
[9]   Perovskite-type oxides -: II.: Redox properties of LaMn1-xCuxO3 and LaCo1-xCuxO3 and methane catalytic combustion [J].
Lisi, L ;
Bagnasco, G ;
Ciambelli, P ;
De Rossi, S ;
Porta, P ;
Russo, G ;
Turco, M .
JOURNAL OF SOLID STATE CHEMISTRY, 1999, 146 (01) :176-183
[10]   Oxygen stoichiometries in La1-xSrxCo1-yFeyO3-δ perovskites at reduced oxygen partial pressures [J].
Mantzavinos, D ;
Hartley, A ;
Metcalfe, IS ;
Sahibzada, M .
SOLID STATE IONICS, 2000, 134 (1-2) :103-109