The formaldehyde sensitivity of LaFe1-xZnxO3-based gas sensor

被引:45
作者
Huang, Shanxing
Qin, Hongwei [1 ]
Song, Peng
Liu, Xing
Li, Lun
Zhang, Rui
Hu, Jifan
Yan, Hongdan
Jiang, Minhua
机构
[1] Shandong Univ, State Key Lab Crystal Mat, Jinan 250100, Peoples R China
[2] Shandong Univ, Dept Phys, Jinan 250100, Peoples R China
[3] Kunming Univ Sci & Technol, Dept Phys, Kunming, Peoples R China
基金
中国国家自然科学基金;
关键词
D O I
10.1007/s10853-007-1991-1
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
Rare earth oxides LaFe1-x Zn (x) O-3 were synthesized by sol-gel method. The X-ray diffraction patterns (XRD) showed that LaFe1-x Zn (x) O(3)oxides are single phase with orthorhombic perovskite structure, they all show p-type semiconducting properties. Among nanocrystalline LaFe1-x Zn (x) O-3 oxides, LaFe0.77Zn0.23O3 exhibits the highest sensitivity of 44.5 to 100 ppm formaldehyde. The optimal working temperature was found to be around 240 degrees C. Moreover the LaFe0.77Zn0.23O3 exhibites short response and recovery time to 100 ppm formaldehyde. The lattice parameter doesn't agree with Vegard's law with the increasing Zn content, and the relative density was 70-80%.
引用
收藏
页码:9973 / 9977
页数:5
相关论文
共 18 条
[11]   Fabrication of La1-xSrxFe1-yCoyO3 sensitive ceramics, nanocrystalline thin films and the manufacture of the NCTF-OSFET gas sensing device [J].
Peng, ZY ;
Li, X ;
Zhao, MY ;
Cai, H ;
Zhao, SQ ;
Hu, GD ;
Xu, BK .
THIN SOLID FILMS, 1996, 286 (1-2) :270-273
[12]   The structure, electrical and ethanol-sensing properties of La1-xPbxFeO3 perovskite ceramics with x≤0.3 [J].
Song, P ;
Qin, HW ;
Zhang, L ;
An, K ;
Lin, ZJ ;
Hu, JF ;
Jiang, MH .
SENSORS AND ACTUATORS B-CHEMICAL, 2005, 104 (02) :312-316
[13]   Preparation and ethanol sensitivity of nanocrystalline La0.7Pb0.3FeO3-based gas sensor [J].
Song, P ;
Hu, JF ;
Qin, HW ;
Zhang, L ;
An, K .
MATERIALS LETTERS, 2004, 58 (21) :2610-2613
[14]   Influence of Sr content on the ethanol sensitivity of nanocrystalline La1-xSrxFeO3 [J].
Suo, H ;
Wang, J ;
Wu, FQ ;
Liu, GF ;
Xu, BK ;
Zhao, MY .
JOURNAL OF SOLID STATE CHEMISTRY, 1997, 130 (01) :152-153
[15]   Gas sensing with semiconducting perovskite oxide LaFeO3 [J].
Toan, NN ;
Saukko, S ;
Lantto, V .
PHYSICA B-CONDENSED MATTER, 2003, 327 (2-4) :279-282
[16]   Air quality prediction by using semiconducting gas sensor with newly fabricated SmFeO3 film [J].
Tomoda, M ;
Okano, S ;
Itagaki, Y ;
Aono, H ;
Sadaoka, Y .
SENSORS AND ACTUATORS B-CHEMICAL, 2004, 97 (2-3) :190-197
[17]   Preparation and gas-sensing properties of perovskite-type SrFeO3 oxide [J].
Wang, YD ;
Chen, JB ;
Wu, XH .
MATERIALS LETTERS, 2001, 49 (06) :361-364
[18]   Formaldehyde-sensing characteristics of perovskite La0.68Pb0.32FeO3 nano-materials [J].
Zhang, L ;
Hu, JF ;
Song, P ;
Qin, HW ;
Liu, XD ;
Jiang, MH .
PHYSICA B-CONDENSED MATTER, 2005, 370 (1-4) :259-263