Ionic liquids are not always green: hydrolysis of 1-butyl-3-methylimidazolium hexafluorophosphate

被引：858

作者：

Swatloski, RP

Holbrey, JD

Rogers, RD

机构：

[1] Univ Alabama, Ctr Green Mfg, Tuscaloosa, AL 35487 USA

[2] Univ Alabama, Dept Chem, Tuscaloosa, AL 35487 USA

来源：

GREEN CHEMISTRY | 2003年 / 5卷 / 04期

关键词：

D O I：

10.1039/b304400a

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

1-Butyl-3-methylimidazolium fluoride hydrate has been identified crystallographically as a decomposition product created during purification of the hydrophobic ionic liquid 1-butyl-3-methylimidazolium hexafluorophosphate. This highlights the need to treat ionic liquids much as one would any other research chemical with potentially hazardous properties, unknown toxicity and/or stability, particularly when searching for 'green solvents'.

引用

页码：361 / 363

页数：3

共 25 条

[21]

Wasserscheid P, 2000, ANGEW CHEM INT EDIT, V39, P3772, DOI 10.1002/1521-3773(20001103)39:21<3772::AID-ANIE3772>3.0.CO

[22]

2-5

[23]

WASSERSCHEID P, 2002, IONIC LIQUDS SYNTHES

[24] Room-temperature ionic liquids. Solvents for synthesis and catalysis [J].