Epoxy-silicone filled with multi-walled carbon nanotubes and carbonyl iron particles as a microwave absorber

被引:332
作者
Qing, Yuchang [1 ]
Zhou, Wancheng [1 ]
Luo, Fa [1 ]
Zhu, Dongmei [1 ]
机构
[1] Northwestern Polytech Univ, State Key Lab Solidificat Proc, Sch Mat Sci & Engn, Xian 710072, Peoples R China
关键词
COMPLEX PERMITTIVITY; ELECTROMAGNETIC PROPERTIES; ELECTRICAL-PROPERTIES; DIELECTRIC-PROPERTIES; MAGNETIC-PROPERTIES; POLYMER COMPOSITES; DOMAIN-WALL; X-BAND; ABSORPTION; PERMEABILITY;
D O I
10.1016/j.carbon.2010.07.014
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
Microwave absorbing composites with epoxy-silicone as matrix and both multi-walled carbon nanotubes (MWCNTs) and carbonyl iron (CI) particles as absorbers were prepared, and their electromagnetic and microwave absorbing properties were investigated in the frequency range of 2-18 GHz. The microstructures of the composites show a uniform dispersion of the MWCNTs and CI particles in the matrix. The complex permittivity of the composites increased with increasing MWCNT content. A double resonance behavior of the complex permeability has been observed. One is due to the domain wall motion at about 7.5 GHz and the other is due to spin rotation at about 13.5 GHz. Reflection loss values exceeding -5 dB can be obtained in the frequency range of 10.4-18, 4.4-18 and 2-18 GHz, when the composite thickness is 0.5, 1 and 1.5 mm, respectively. A minimum reflection loss of -16.9 dB at 10.5 GHz and a bandwidth over the frequency range of 3.4-18 GHz with reflection loss below -10 dB can obtained for a composite filled with 0.5 vol% MWCNT and SO vol% CI particles. (C) 2010 Elsevier Ltd. All rights reserved.
引用
收藏
页码:4074 / 4080
页数:7
相关论文
共 48 条
[11]   MOBILITY AND OR DAMPING OF THE DOMAIN-WALL - COMPARISON BETWEEN EXPERIMENTAL AND THEORETICAL VALUES IN FERRIMAGNETS [J].
GUYOT, M ;
MERCERON, T ;
CAGAN, V ;
MESSEKHER, A .
PHYSICA STATUS SOLIDI A-APPLIED RESEARCH, 1988, 106 (02) :595-612
[12]   TEMPERATURE-DEPENDENCE OF THE DOMAIN-WALL MOBILITY IN YIG, DEDUCED FROM THE FREQUENCY-SPECTRA OF THE INITIAL SUSCEPTIBILITY OF POLYCRYSTALS [J].
GUYOT, M ;
CAGAN, V .
JOURNAL OF MAGNETISM AND MAGNETIC MATERIALS, 1982, 27 (02) :202-208
[13]   Doping effect of multiwall carbon nanotubes on the microwave electromagnetic properties of NiCoZn spinel ferrites [J].
Han, Mangui ;
Deng, Longjiang .
APPLIED PHYSICS LETTERS, 2007, 90 (01)
[14]   HELICAL MICROTUBULES OF GRAPHITIC CARBON [J].
IIJIMA, S .
NATURE, 1991, 354 (6348) :56-58
[15]   Carbon nanotubes loaded with magnetic particles [J].
Korneva, G ;
Ye, HH ;
Gogotsi, Y ;
Halverson, D ;
Friedman, G ;
Bradley, JC ;
Kornev, KG .
NANO LETTERS, 2005, 5 (05) :879-884
[16]   Electromagnetic properties of composites containing elongated conducting inclusions [J].
Lagarkov, AN ;
Sarychev, AK .
PHYSICAL REVIEW B, 1996, 53 (10) :6318-6336
[17]   Electromagnetic interference (EMI) shielding of single-walled carbon nanotube epoxy composites [J].
Li, Ning ;
Huang, Yi ;
Du, Feng ;
He, Xiaobo ;
Lin, Xiao ;
Gao, Hongjun ;
Ma, Yanfeng ;
Li, Feifei ;
Chen, Yongsheng ;
Eklund, Peter C. .
NANO LETTERS, 2006, 6 (06) :1141-1145
[18]   Large dielectric constant of the chemically functionalized carbon nanotube/polymer composites [J].
Li, Qun ;
Xue, Qingzhong ;
Hao, Lanzhong ;
Gao, Xili ;
Zheng, Qingbin .
COMPOSITES SCIENCE AND TECHNOLOGY, 2008, 68 (10-11) :2290-2296
[19]   Microwave-absorbing properties of Co-filled carbon nanotubes [J].
Lin, Haiyan ;
Zhu, Hong ;
Guo, Hongfan ;
Yu, Liufang .
MATERIALS RESEARCH BULLETIN, 2008, 43 (10) :2697-2702
[20]   Clay assisted dispersion of carbon nanotubes in conductive epoxy nanocomposites [J].
Liu, Lei ;
Grunlan, Jaime C. .
ADVANCED FUNCTIONAL MATERIALS, 2007, 17 (14) :2343-2348