Mechanistic aspects of C-H activation by Pt complexes

被引:675
作者
Lersch, M [1 ]
Tilset, M [1 ]
机构
[1] Univ Oslo, Dept Chem, N-0315 Oslo, Norway
关键词
D O I
10.1021/cr030710y
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Pt has much to offer in the realm of C-H activation. The strong Pt-H and Pt-C bonds that can be formed in a C-H activation reaction undoubtedly contribute to the success of Pt. Hydrocarbon activation, the first step in the Shilov cycle, is probably the most intensely explored and best understood of the three steps. The C-H activation step is expected to continue to fascinate chemists for years to come. Examples are presented that C-H activation can occur at electron-rich and electron-poor Pt complexes.
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收藏
页码:2471 / 2526
页数:56
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