学术探索
学术期刊
新闻热点
数据分析
智能评审

Mechanistic aspects of C-H activation by Pt complexes

被引：675
作者：
Lersch, M [1 ]
Tilset, M [1 ]
机构：
[1] Univ Oslo, Dept Chem, N-0315 Oslo, Norway
来源：
CHEMICAL REVIEWS | 2005年 / 105卷 / 06期
关键词：
D O I：
10.1021/cr030710y
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Pt has much to offer in the realm of C-H activation. The strong Pt-H and Pt-C bonds that can be formed in a C-H activation reaction undoubtedly contribute to the success of Pt. Hydrocarbon activation, the first step in the Shilov cycle, is probably the most intensely explored and best understood of the three steps. The C-H activation step is expected to continue to fascinate chemists for years to come. Examples are presented that C-H activation can occur at electron-rich and electron-poor Pt complexes.
引用
收藏
页码：2471 / 2526
页数：56
相关论文
共 347 条
  • [11] ANDERSON JR, 1957, ADV CATAL, V9, P51
  • [12] [Anonymous], 1987, MECH THEORY ORGANIC
  • [13] ALCOHOL COMPLEXES OF PLATINUM(II) - SYNTHESES AND CRYSTAL-STRUCTURES OF [S-(R-STAR,R-STAR)]-(+)589-[PT(OSO2CF3)2(1,2-C6H4(PMEPH)2)] AND [S-(R-STAR,R-STAR)]-(+)589-[PT(HOCH2CH2OH)(1,2-C6H4(PMEPH)2)](CF3SO3)2
    APPELT, A
    ARIARATNAM, V
    WILLIS, AC
    WILD, SB
    [J]. TETRAHEDRON-ASYMMETRY, 1990, 1 (01) : 9 - 12
  • [14] Catalysis research of relevance to carbon management: Progress, challenges, and opportunities
    Arakawa, H
    Aresta, M
    Armor, JN
    Barteau, MA
    Beckman, EJ
    Bell, AT
    Bercaw, JE
    Creutz, C
    Dinjus, E
    Dixon, DA
    Domen, K
    DuBois, DL
    Eckert, J
    Fujita, E
    Gibson, DH
    Goddard, WA
    Goodman, DW
    Keller, J
    Kubas, GJ
    Kung, HH
    Lyons, JE
    Manzer, LE
    Marks, TJ
    Morokuma, K
    Nicholas, KM
    Periana, R
    Que, L
    Rostrup-Nielson, J
    Sachtler, WMH
    Schmidt, LD
    Sen, A
    Somorjai, GA
    Stair, PC
    Stults, BR
    Tumas, W
    [J]. CHEMICAL REVIEWS, 2001, 101 (04) : 953 - 996
  • [15] Looking for stable carbenes: The difficulty in starting anew
    Arduengo, AJ
    [J]. ACCOUNTS OF CHEMICAL RESEARCH, 1999, 32 (11) : 913 - 921
  • [16] SELECTIVE INTERMOLECULAR CARBON-HYDROGEN BOND ACTIVATION BY SYNTHETIC METAL-COMPLEXES IN HOMOGENEOUS SOLUTION
    ARNDTSEN, BA
    BERGMAN, RG
    MOBLEY, TA
    PETERSON, TH
    [J]. ACCOUNTS OF CHEMICAL RESEARCH, 1995, 28 (03) : 154 - 162
  • [17] UNUSUALLY MILD AND SELECTIVE HYDROCARBON C-H BOND ACTIVATION WITH POSITIVELY CHARGED IRIDIUM(III) COMPLEXES
    ARNDTSEN, BA
    BERGMAN, RG
    [J]. SCIENCE, 1995, 270 (5244) : 1970 - 1973
  • [18] Atwood J.D., 1997, INORGANIC ORGANOMETA, V2nd
  • [19] Stereoselective formation of (aminoalkyl)platinum complexes from imines
    Baar, CR
    Carbray, LP
    Jennings, MC
    Puddephatt, RJ
    Vittal, JJ
    [J]. ORGANOMETALLICS, 2001, 20 (03) : 408 - 417
  • [20] Novel T-shaped 14-electron platinum(II) complexes stabilized by one agostic interaction
    Baratta, W
    Stoccoro, S
    Doppiu, A
    Herdtweck, E
    Zucca, A
    Rigo, P
    [J]. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2003, 42 (01) : 105 - 108
12345678910