Click chemistry produces hyper-cross-linked polymers with tetrahedral cores

被引：56

作者：

Plietzsch, Oliver ^{[2
,3
]}

Schilling, Christine I. ^{[2
,3
]}

Grab, Tobias ^{[4
]}

Grage, Stephan L. ^{[5
]}

Ulrich, Anne S. ^{[2
,3
,5
]}

Comotti, Angiolina ^{[1
]}

Sozzani, Piero ^{[1
]}

Muller, Thierry ^{[2
,3
]}

Braese, Stefan ^{[2
,3
]}

机构：

[1] Univ Milano Bicocca, Dept Mat Sci, I-20125 Milan, Italy

[2] Karlsruhe Inst Technol, Inst Organ Chem, D-76131 Karlsruhe, Germany

[3] DFG Ctr Funct Nanostruct CFN, D-76131 Karlsruhe, Germany

[4] Cynora GmbH, D-76344 Eggenstein Leopoldshafen, Germany

[5] KIT, Inst Biol Interfaces IBG2, D-76021 Karlsruhe, Germany

来源：

NEW JOURNAL OF CHEMISTRY | 2011年 / 35卷 / 08期

关键词：

INTRINSIC MICROPOROSITY PIMS; ADHESIVE POLYMERS; POWERFUL TOOL; POLYMERIZATION; NETWORKS; CYCLOADDITION; FRAMEWORKS; AZIDES;

D O I：

10.1039/c1nj20370c

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Methane and adamantane based hyper-cross-linked polymers have been prepared by click chemistry reacting the corresponding tetraalkynes with 1,4-diazidobenzene. The adamantane based HCP proved to be very efficient for CO2 capture at low pressures.

引用

页码：1577 / 1581

页数：5

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