A selective synthesis of biphenyl by the Pd(OAc)2/MoO2(acac)2/O2/AcOH catalyst system

被引:28
作者
Okamoto, M [1 ]
Yamaji, T [1 ]
机构
[1] Kyushu Univ, Grad Sch Engn, Dept Chem & Biochem, Fukuoka 8128581, Japan
关键词
D O I
10.1246/cl.2001.212
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
A high selectivity of biphenyl (88%) was attained by the Pd-catalyzed dimerization of benzene in the presence of O-2 and acetic acid when MoO2(acac)(2) was used as a cocatalyst. Various Mo compounds gave high selectivities of biphenyl (82-87%).
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页码:212 / 213
页数:2
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