Simultaneous generation of anionic and neutral palladium(II) complexes from η3-allylpalladium chloride dimer and fluorinated β-enaminones

被引：5

作者：

Bouquillon, S

Bouillon, JP

Thomas, L

Plantier-Royon, R

Chanteau, F

Tinant, B

Hénin, F

Portella, C

Muzart, J

机构：

[1] Univ Reims, CNRS, Unite Mixte Rech React Select & Applicat, F-51687 Reims 2, France

[2] CSTR, Unite Cristallog, B-1348 Louvain, Belgium

来源：

EUROPEAN JOURNAL OF ORGANIC CHEMISTRY | 2003年 / 2003卷 / 24期

关键词：

allyl ligands; N; O ligands; palladium; perfluorinated ligands;

D O I：

10.1002/ejoc.200300557

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Reactions between eta(3)-allylpalladium chloride dimer, 1,8-di-azabicyclo[5.4.0]undec-7-ene (DBU) and 1-amino-2-fluoro-1-perfluoroethyl-3 -phenylprop-1-en-3-one or 1,12-diamino-2,11-difluoro-1,12-bis(perfluorobutyl)dodeca-1,11-diene- 3,10-dione simultaneously provided two types of Pd-II complexes. One is an anionic eta(3)-allylpalladium complex with protonated DBU as counterion while the other is a neutral eta(3)-allyl(beta-ketoiminato)palladium complex. A mechanism involving the amidine function of DBU in the formation of the two complexes is proposed. ((C) Wiley-VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2003)

引用

页码：4717 / 4720

页数：4

共 24 条

[1] AMINATION OF PI-ALLYLPALLADIUM CHLORIDE COMPLEXES - A MECHANISTIC STUDY [J].