Templated encapsulation of pyridyl-bian palladium complexes:: Tunable catalysts for CO/4-tert-butylstyrene copolymerization

被引：64

作者：

Flapper, Jitte ^{[1
]}

Reek, Joost N. H. ^{[1
]}

机构：

[1] Univ Amsterdam, Vant Hoff Inst Mol Sci, NL-1018 WV Amsterdam, Netherlands

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2007年 / 46卷 / 45期

关键词：

homogeneous catalysis; palladium; polymerization self-assembly; supramolecular catalysis;

D O I：

10.1002/anie.200703294

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

(Chemical Equation Presented) Tuning with zinc: Palladium complexes of 3-pyridyl-bian (see scheme, blue) provide active catalysts for the copolymerization of CO and 4-tert-butylstyrene, but only after encapsulation by two zinc salphen building blocks (red). The catalyst properties depend on the salphen units, giving rise to novel tools for catalyst tuning. © 2007 Wiley-VCH Verlag GmbH & Co. KGaA.

引用

页码：8590 / 8592

页数：3

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