Coupled-channel statistical theory of the N(2D)+H2 and O(1D)+H2 insertion reactions

被引：181

作者：

Rackham, EJ ^{[1
]}

Huarte-Larranaga, F ^{[1
]}

Manolopoulos, DE ^{[1
]}

机构：

[1] Phys & Theoret Chem Lab, S Pks Rd, Oxford OX1 3QZ, England

来源：

CHEMICAL PHYSICS LETTERS | 2001年 / 343卷 / 3-4期

基金：

英国工程与自然科学研究理事会;

关键词：

D O I：

10.1016/S0009-2614(01)00707-2

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

A detailed statistical theory of atom-diatom insertion reactions is derived by combining the early statistical ideas of Pechukas and Light with the coupled-channel capture theory of Clary and Henshaw. The theory is applied to the N(D-2) + H-2 and O(D-1) + H-2 reactions and found to give results in good agreement with the exact quantum mechanical integral cross sections reported recently by Honvault and Launay. (C) 2001 Elsevier Science BN. All rights reserved.

引用

页码：356 / 364

页数：9

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