Enyne metathesis: A catalytic, cross-selective diene synthesis

被引：16

作者：

Diver, ST ^{[1
]}

Giessert, AJ ^{[1
]}

机构：

[1] SUNY Buffalo, Dept Chem, Buffalo, NY 14260 USA

来源：

SYNTHESIS-STUTTGART | 2004年 / 03期

关键词：

enyne metathesis; Grubbs' carbene catalysts; 1,3-dienes;

D O I：

10.1055/s-2003-44375

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Methods for the synthesis of 1,3-dienes by intermolecular enyne metathesis are described. A brief overview of enyne metathesis is provided with a discussion of the scope and limitations with respect to reactants and catalyst. The surge of recent interest in metathesis generally and the cross enyne metathesis specifically, has closely matched the development of the functional group-tolerant Grubbs' carbene catalysts.

引用

收藏

页码：466 / 471

页数：6

相关论文

共 76 条

[1]

Ackermann L, 2001, SYNLETT, P397

[2] Ruthenium carbene complexes with imidazolin-2-ylidene ligands allow the formation of tetrasubstituted cycloalkenes by RCM [J].

Ackermann, L ;

Fürstner, A ;

Weskamp, T ;

Kohl, FJ ;

Herrmann, WA .

TETRAHEDRON LETTERS, 1999, 40 (26) :4787-4790

[3] A recyclable 'boomerang' polymer-supported ruthenium catalyst for olefin metathesis [J].

Ahmed, M ;

Barrett, AGM ;

Braddock, DC ;

Cramp, SM ;

Procopiou, PA .

TETRAHEDRON LETTERS, 1999, 40 (49) :8657-8662

[4]

Ahmed M, 2000, SYNLETT, P1007

[5] A convenient method for the efficient removal of ruthenium byproducts generated during olefin metathesis reactions [J].

Ahn, YM ;

Yang, K ;

Georg, GI .

ORGANIC LETTERS, 2001, 3 (09) :1411-1413

[6] The behavior of 1,n-enynes in the presence of transition metals [J].

Aubert, C ;

Buisine, O ;

Malacria, M .

CHEMICAL REVIEWS, 2002, 102 (03) :813-834

[7] New approaches to olefin cross-metathesis [J].

Blackwell, HE ;

O'Leary, DJ ;

Chatterjee, AK ;

Washenfelder, RA ;

Bussmann, DA ;

Grubbs, RH .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2000, 122 (01) :58-71

[8] Synthesis of a highly functionalized tricyclic ring system related to guanacastepene via a tandem ring-closing metathesis reaction [J].

Boyer, FD ;

Hanna, I .

TETRAHEDRON LETTERS, 2002, 43 (42) :7469-7472

[9] Synthesis of trisubstituted alkenes via olefin cross-metathesis [J].

Chatterjee, AK ;

Grubbs, RH .

ORGANIC LETTERS, 1999, 1 (11) :1751-1753

[10]

Clark JS, 2002, TETRAHEDRON, V58, P1973

← 1 2 3 4 5 6 7 8 →