Oxidation of tertiary nitrogen compounds to N-oxides by molecular oxygen-aldehyde system in the absence of metal catalyst

被引：10

作者：

Dongre, RS ^{[1
]}

Rao, TV ^{[1
]}

Sharma, BK ^{[1
]}

Sain, B ^{[1
]}

Bhatia, VK ^{[1
]}

机构：

[1] Indian Inst Petr, Dehra Dun 248005, Uttar Pradesh, India

来源：

SYNTHETIC COMMUNICATIONS | 2001年 / 31卷 / 02期

关键词：

D O I：

10.1081/SCC-100000196

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

A variety of tertiary nitrogen compounds have been oxidized to corresponding N-oxides in near quantitative yields by molecular oxygen/2-methylpropanal system in the absence of metal catalyst.

引用

页码：167 / 172

页数：6

共 33 条

[1] Sharpless asymmetric dihydroxylation on an industrial scale
Ahrgren, L
Sutin, L
[J]. ORGANIC PROCESS RESEARCH & DEVELOPMENT, 1997, 1 (06) : 425 - 427
[2] Albini P., 1991, HETEROCYCLIC N OXIDE, P31
[3] BAUMSTARK AL, 1987, TETRAHEDR LETT, V29, P1963
[4] Mild and efficient flavin-catalyzed H2O2 oxidation of tertiary amines to amine N-oxides
Bergstad, K
Bäckvall, JE
[J]. JOURNAL OF ORGANIC CHEMISTRY, 1998, 63 (19) : 6650 - 6655
[5] REARRANGEMENTS OF N-OXIDES - A NOVEL SYNTHESIS OF PYRIDYL CARBINOLS AND ALDEHYDES
BOEKELHEIDE, V
LINN, WJ
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1954, 76 (05) : 1286 - 1291
[6] BROUGHAM P, 1987, SYNTHESIS-STUTTGART, P1015
[7] NEW METHOD OF PREPARING N-OXIDES FROM POLYHALOGENATED N-HETEROAROMATIC COMPOUNDS
CHIVERS, GE
SUSCHITZKY, H
[J]. JOURNAL OF THE CHEMICAL SOCIETY D-CHEMICAL COMMUNICATIONS, 1971, (01): : 28 - +
[8] Oxidation of secondary alcohols using molecular oxygen and benzaldehyde in the absence of metal catalysts
Choudary, BM
Sudha, Y
[J]. SYNTHETIC COMMUNICATIONS, 1996, 26 (09) : 1651 - 1655
[9] Cope A. C., 1963, ORG SYNTH, VIV, P612
[10] Cope A. C., 1960, ORG REACTIONS, V11, P317

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