A quantitative synthesis of β-carboxylated thiolophosphates via a Michael reaction

被引：8

作者：

Desforges, E ^{[1
]}

Grysan, A ^{[1
]}

Oget, N ^{[1
]}

Sindt, M ^{[1
]}

Mieloszynski, JL ^{[1
]}

机构：

[1] Univ Metz, EA3471, Lab Chim & Applicat, F-57045 Metz, France

来源：

TETRAHEDRON LETTERS | 2003年 / 44卷 / 33期

关键词：

thiophosphoric acid; thiolophosphate; acrylate; Michael reaction;

D O I：

10.1016/S0040-4039(03)01530-2

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Reactions of O,O'-dialkylthiophosphoric acids with acrylates provide a direct synthetic route to beta-carboxylated thiolophosphates. This Michael addition, without solvent, is quantitative at 90degreesC in 1 h for the 2/1 thiophosphoric acid/acrylate ratio. Moreover, this excess of thiophosphoric acid can be reused for further reactions. (C) 2003 Elsevier Ltd. All rights reserved.

引用

页码：6273 / 6276

页数：4

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