First evidence for the use of organosilver compounds in Pd-catalyzed coupling reactions; A mechanistic rationale for the Pd/Ag-catalyzed enyne synthesis?

被引：47

作者：

Dillinger, S ^{[1
]}

Bertus, P ^{[1
]}

Pale, P ^{[1
]}

机构：

[1] Univ Strasbourg, CNRS, Inst Le Bel, Lab Synthese & Reactivite Organ, F-67000 Strasbourg, France

来源：

ORGANIC LETTERS | 2001年 / 3卷 / 11期

关键词：

D O I：

10.1021/ol015830b

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

[GRAPHICS] Silver acetylides have been prepared and used in Pd-catalyzed coupling reactions. Enynes have thus been obtained in good yields. This work demonstrates that organosilver compounds could enter the Pd catalytic cycle; it also supports the role of silver acetylides as intermediates in the new Pd/Ag-catalyzed coupling reaction.

引用

页码：1661 / 1664

页数：4

共 36 条

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