SILVER-CATALYZED HETEROCYCLIZATION - FIRST TOTAL SYNTHESIS OF THE NATURALLY-OCCURRING CIS 2-HEXADECYL-3-HYDROXY-4-METHYLENE BUTYROLACTONE

被引：45

作者：

DALLA, V ^{[1
]}

PALE, P ^{[1
]}

机构：

[1] UFR SCI,CNRS,CHIM ORGAN PHYS LAB,F-51062 REIMS,FRANCE

来源：

TETRAHEDRON LETTERS | 1994年 / 35卷 / 21期

关键词：

SILVER-CATALYZED CYCLIZATION; GAMMA-ALKYLIDENE GAMMA-LACTONES; EXOCYCLIC ENOL LACTONES; 3-HYDROXY-4-METHYLENE BUTYROLACTONES; BETA-HYDROXY-GAMMA-ACETYLENIC ACIDS;

D O I：

10.1016/S0040-4039(00)73226-6

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The title compound was obtained in 4 steps with an overall yield of 64% with the silver-catalyzed cyclization of the corresponding substituted beta- hydroxy-gamma- acetylenic acid as the key-step.

引用

页码：3525 / 3528

页数：4

共 16 条

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