Responsive assemblies: Gold nanoparticles with mixed ligands in microphase separated block copolymers

被引:115
作者
Li, Qifang [2 ]
He, Jinbo
Glogowski, Elizabeth [1 ]
Li, Xuefa [3 ]
Wang, Jin [3 ]
Emrick, Todd [1 ]
Russell, Thomas P. [1 ]
机构
[1] Univ Massachusetts, Dept Polymer Sci & Engn, Amherst, MA 01003 USA
[2] Beijing Inst Chem Technol, State Key Lab Chem Resource Engn, Beijing 100029, Peoples R China
[3] Argonne Natl Lab, Adv Photon Source, Argonne, IL 60439 USA
关键词
D O I
10.1002/adma.200702004
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
A simple method for controlling the spatial distribution of nanoparticles in a diblock copolymer is shown. By varying the ligand functionality of the nanoparticles, as well as the processing conditions, the distribution of gold nanoparticles in the microdomains of the diblock copolymer was controlled and altered. In addition, the nanoparticles are found to affect the diblock copolymer morphologies. Thermal treatment caused a redistribution of the nanoparticles inside one microdomain.
引用
收藏
页码:1462 / +
页数:6
相关论文
共 35 条
[1]   Kinetically driven self assembly of highly ordered nanoparticle monolayers [J].
Bigioni, TP ;
Lin, XM ;
Nguyen, TT ;
Corwin, EI ;
Witten, TA ;
Jaeger, HM .
NATURE MATERIALS, 2006, 5 (04) :265-270
[2]   Size-selective organization of enthalpic compatibilized nanocrystals in ternary block copolymer/particle mixtures [J].
Bockstaller, MR ;
Lapetnikov, Y ;
Margel, S ;
Thomas, EL .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2003, 125 (18) :5276-5277
[3]   Hierarchical nanoparticle assemblies formed by decorating breath figures [J].
Böker, A ;
Lin, Y ;
Chiapperini, K ;
Horowitz, R ;
Thompson, M ;
Carreon, V ;
Xu, T ;
Abetz, C ;
Skaff, H ;
Dinsmore, AD ;
Emrick, T ;
Russell, TP .
NATURE MATERIALS, 2004, 3 (05) :302-306
[4]   Cavitated block copolymer micellar thin films: Lateral arrays of open nanoreactors [J].
Boontongkong, Y ;
Cohen, RE .
MACROMOLECULES, 2002, 35 (09) :3647-3652
[5]   SYNTHESIS OF THIOL-DERIVATIZED GOLD NANOPARTICLES IN A 2-PHASE LIQUID-LIQUID SYSTEM [J].
BRUST, M ;
WALKER, M ;
BETHELL, D ;
SCHIFFRIN, DJ ;
WHYMAN, R .
JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1994, (07) :801-802
[6]   SIZE EFFECT ON MELTING TEMPERATURE OF GOLD PARTICLES [J].
BUFFAT, P ;
BOREL, JP .
PHYSICAL REVIEW A, 1976, 13 (06) :2287-2298
[7]   Control of nanoparticle location in block copolymers [J].
Chiu, JJ ;
Kim, BJ ;
Kramer, EJ ;
Pine, DJ .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2005, 127 (14) :5036-5037
[8]   Gold nanoparticles: Assembly, supramolecular chemistry, quantum-size-related properties, and applications toward biology, catalysis, and nanotechnology [J].
Daniel, MC ;
Astruc, D .
CHEMICAL REVIEWS, 2004, 104 (01) :293-346
[9]   2-DIMENSIONAL CRYSTALLIZATION [J].
DENKOV, ND ;
VELEV, OD ;
KRALCHEVSKY, PA ;
IVANOV, IB ;
YOSHIMURA, H ;
NAGAYAMA, K .
NATURE, 1993, 361 (6407) :26-26
[10]   Divalent metal nanoparticles [J].
DeVries, Gretchen A. ;
Brunnbauer, Markus ;
Hu, Ying ;
Jackson, Alicia M. ;
Long, Brenda ;
Neltner, Brian T. ;
Uzun, Oktay ;
Wunsch, Benjamin H. ;
Stellacci, Francesco .
SCIENCE, 2007, 315 (5810) :358-361