Chemistry of 3,4-epoxy-2-methylene oxolanes: Highly diastereoselective electrophilic additions.

被引：12

作者：

Dalla, V ^{[1
]}

Pale, P ^{[1
]}

机构：

[1] UNIV REIMS,CNRS,CHIM PHYS ORGAN LAB,F-51100 REIMS,FRANCE

来源：

TETRAHEDRON LETTERS | 1996年 / 37卷 / 16期

关键词：

D O I：

10.1016/0040-4039(96)00441-8

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

electrophilic additions to the enol ether part of 3,4-epoxy-2-methylene oxolanes are described. The isomer resulting from an anti addition relative to the oxirane substituent was predominantly obtained. With phenylselenyl bromine as electrophile, a complete diastereoselectivity was achieved again in favor of the trans isomer. Copyright (C) 1996 Published by Elsevier Science Ltd

引用

页码：2777 / 2780

页数：4

共 12 条

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