Novel lithium 3-sila- and 3-germa-β-diketiminates

被引：26

作者：

Hitchcock, PB ^{[1
]}

Lappert, MF ^{[1
]}

Layh, M ^{[1
]}

机构：

[1] Univ Sussex, Chem Lab, Brighton BN1 9QJ, E Sussex, England

来源：

CHEMICAL COMMUNICATIONS | 1998年 / 20期

关键词：

D O I：

10.1039/a805864d

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The novel 3-sila- and 3-germa-beta-diketiminates [Li{N(R)C(Ar)E(R)C(Ar)N(R)}(D)(n)] (R = SiMe3, Ar = C6H3Me2-2,6 or Ph, E = Si or Ge, D = thf or ArCN and n = 1 or 2) were obtained from the reaction of [Li(ER3)(thf)(3)] with PhCN or ArCN; the X-ray crystal structures of two representatives of this new class of compounds were determined and shown to have, in contrast to related carbon analogues, the anionic charge localised at Si or Ge.

引用

页码：2179 / 2180

页数：2

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