Ferromagnetic langmuir-Blodgett film based on Prussian blue

被引:104
作者
Mingotaud, C [1 ]
Lafuente, C [1 ]
Amiell, J [1 ]
Delhaes, P [1 ]
机构
[1] CNRS, Ctr Rech Paul Pascal, F-33600 Pessac, France
关键词
D O I
10.1021/la981177y
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
For the first time, new hybrid organic-inorganic materials containing ferri-ferrocyanide and having a well-defined multilayer architecture were successfully obtained using the Langmuir-Blodgett (LB) technique. These LB films present a ferromagnetic behavior below 5.7 K. In this temperature range, their magnetic properties are clearly anisotropic, as expected from the lamellar structure. Finally, they are the first case of a new series of lamellar materials in which the magnetic properties of the inorganic sheets can be combined with other functions arising from the amphiphilic part.
引用
收藏
页码:289 / 292
页数:4
相关论文
共 20 条
[1]   Magnetic Langmuir-Blodgett films with metal-oxalato complexes [J].
Aiai, M ;
Ramos, J ;
Mingotaud, C ;
Amiell, J ;
Delhaes, P ;
Jaiswal, A ;
Singh, RA ;
Singh, B ;
Singh, BP .
CHEMISTRY OF MATERIALS, 1998, 10 (03) :728-733
[2]  
BENNER H, 1990, PHYSICS CHEM MATERIA, V9, P323
[3]   STRUCTURES AND SOLID-STATE REACTIONS OF PRUSSIAN BLUE ANALOGS CONTAINING CHROMIUM MANGANESE IRON AND COBALT [J].
BROWN, DB ;
SHRIVER, DF .
INORGANIC CHEMISTRY, 1969, 8 (01) :37-&
[4]   Toward new organic/inorganic superlattices: Keggin polyoxometalates in Langmuir and Langmuir-Blodgett films [J].
ClementeLeon, M ;
Agricole, B ;
Mingotaud, C ;
GomezGarcia, CJ ;
Coronado, E ;
Delhaes, P .
LANGMUIR, 1997, 13 (08) :2340-2347
[5]   Application of the Langmuir-Blodgett technique to polyoxometalates: Towards new magnetic films [J].
ClementeLeon, M ;
Mingotaud, C ;
Agricole, B ;
GomezGarcia, CJ ;
Coronado, E ;
Delhaes, P .
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH, 1997, 36 (10) :1114-1116
[6]  
DAY P, 1985, PHILOS T R SOC A, V314, P145, DOI 10.1098/rsta.1985.0015
[7]   NEW 3-DIMENSIONAL FERRIMAGNETIC MATERIALS - K2MN[MN(CN)(6)], MN-3[MN(CN)(6)]CENTER-DOT(2)12H2O, AND CSMN[MN(CN)(6)]CENTER-DOT-1/2H2O [J].
ENTLEY, WR ;
GIROLAMI, GS .
INORGANIC CHEMISTRY, 1994, 33 (23) :5165-5166
[8]   A ROOM-TEMPERATURE ORGANOMETALLIC MAGNET BASED ON PRUSSIAN BLUE [J].
FERLAY, S ;
MALLAH, T ;
OUAHES, R ;
VEILLET, P ;
VERDAGUER, M .
NATURE, 1995, 378 (6558) :701-703
[9]  
GADET V, 1992, THESIS P M CURIE PAR
[10]   NEUTRON-DIFFRACTION STUDY OF PRUSSIAN BLUE, FE4[FE(CN)6]3.XH2O - LOCATION OF WATER-MOLECULES AND LONG-RANGE MAGNETIC ORDER [J].
HERREN, F ;
FISCHER, P ;
LUDI, A ;
HALG, W .
INORGANIC CHEMISTRY, 1980, 19 (04) :956-959