Interaction of cobalt(II) and nickel(II) with a γ-linked, bis-β-diketone ligand to yield an unusual coordination motif

被引：8

作者：

Zheng, BS

Zhang, XY

Zhu, HW

Luo, SX

Lindoy, LF ^{[1
]}

McMurtrie, JC

Turner, P

Wei, G

机构：

[1] Guizhou Normal Univ, Sch Phys & Chem, Guiyang 550001, Guizhou, Peoples R China

[2] Univ Sydney, Sch Chem, Ctr Heavy Met Res, Sydney, NSW 2006, Australia

[3] CSIRO, Ind Phys, Lindfield, NSW 2070, Australia

来源：

DALTON TRANSACTIONS | 2005年 / 08期

关键词：

D O I：

10.1039/b502334c

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Discrete cobalt(II) and nickel(II) complexes of type ML (where L is a bis(2,4-pentanedionate) derivative incorporating a -SCH2CH2S- bridge between the gamma-carbons of respective beta-diketone units) have been synthesised and represent the first examples in which a gamma-substituted, thioether-containing beta-diketone ligand coordinates via a sulfur and oxygen donor in preference to the classical coordination mode involving both beta-diketonate oxygens.

引用

页码：1349 / 1351

页数：3

共 14 条

[1] SIR97:: a new tool for crystal structure determination and refinement
Altomare, A
Burla, MC
Camalli, M
Cascarano, GL
Giacovazzo, C
Guagliardi, A
Moliterni, AGG
Polidori, G
Spagna, R
[J]. JOURNAL OF APPLIED CRYSTALLOGRAPHY, 1999, 32 : 115 - 119
[2] Burnett M.N., 1996, ORTEP-III: Oak Ridge Thermal Ellipsoid Plot Program for Crystal Structure Illustrations
[3] Triangles and tetrahedra: metal directed self-assembly of metallo-supramolecular structures incorporating bis-b-diketonato ligands
Clegg, JK
Lindoy, LF
Moubaraki, B
Murray, KS
McMurtrie, JC
[J]. DALTON TRANSACTIONS, 2004, (16) : 2417 - 2423
[4] ORTEP-3 for Windows - a version of ORTEP-III with a Graphical User Interface (GUI)
[J]. Journal of Applied Crystallography, 1997, 30 (pt 5)
[5] Synthesis and characterization of sulfur-bridged binuclear β-diketonatoruthenium complexes and a monomeric ruthenium complex.: Crystal and molecular structures of racemic and meso isomers of [Ru(acac)2(μ-topd-O,S,O′)Ru(acac)2] (acac = acetylacetonato and topd = 3-thioxo-2,4-pentanedione)
Hashimoto, T
Endo, A
Nagao, N
Sato, GP
Natarajan, K
Shimizu, K
[J]. INORGANIC CHEMISTRY, 1998, 37 (20) : 5211 - 5220
[6] Functional porous coordination polymers
Kitagawa, S
Kitaura, R
Noro, S
[J]. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2004, 43 (18) : 2334 - 2375
[7] Lindoy L.F., 2000, SELF ASSEMBLY SUPRAM
[8] Crystal and molecular structure of a novel mixed ligand complex of tin(IV), [(Et(2)NCS(2))(2)Sn(O-C(CH3)=C(S)-C(O)-CH3)]
Sharma, S
Bohra, R
Mehrotra, RC
[J]. POLYHEDRON, 1996, 15 (09) : 1525 - 1529
[9] Sheldrick G.M., 1998, Tammanstrasse 4, D-3400
[10] Chloromethylthio-substituted chromium(III), cobalt(III), and aluminum(III) acetylacetonates
Svistunova, IV
Shapkin, NP
Svistunov, GM
[J]. RUSSIAN JOURNAL OF GENERAL CHEMISTRY, 2001, 71 (09) : 1355 - 1357

← 1 2 →