Copper(II)-catalysed aerobic oxidation of primary alcohols to aldehydes

被引:481
作者
Gamez, P
Arends, IWCE
Reedijk, J
Sheldon, RA
机构
[1] Delft Univ Technol, Dept Biotechnol, Lab Biocatalysis & Organ Chem, NL-2628 BL Delft, Netherlands
[2] Leiden Univ, Leiden Inst Chem, Gorlaeus Labs, NL-2300 RA Leiden, Netherlands
关键词
D O I
10.1039/b308668b
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
[CuBr2(2,2'-bipyridine)] catalyses the selective and very mild aerobic oxidation of primary alcohols to aldehydes in acetonitrile : water (2 : 1) in the presence of 2,2,6,6-tetramethylpiperidinyl-1-oxy (TEMPO) and a base as cocatalysts.
引用
收藏
页码:2414 / 2415
页数:2
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