Building blocks for self-assembled porphyrinic photonic wires

被引:72
作者
Koepf, M
Trabolsi, A
Elhabiri, M
Wytko, JA
Paul, D
Albrecht-Gary, AM
Weiss, J
机构
[1] Univ Strasbourg, Lab Phys Chim Bioinorgan, UMR 7509, CNRS,ECPM, F-67200 Strasbourg, France
[2] Univ Strasbourg, Lab Chim Ligands Architecture Controlee, Inst Chim, F-67070 Strasbourg, France
关键词
D O I
10.1021/ol050033p
中图分类号
O62 [有机化学];
学科分类号
070303 ; 081704 ;
摘要
Based on the high affinity of phenanthroline-strapped porphyrins for imidazoles, building blocks for self-assembled, linear porphyrin architectures have been designed. Their synthesis is reported, and the assembly principle is illustrated by the formation of the shortest possible scaffold. Only one type of assembly is observed, and the stepwise energy transfer from the boron dipyrrylmethane (BODIPY) input to the free base output is highly efficient.
引用
收藏
页码:1279 / 1282
页数:4
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