Polyethylene oxide (PEO) ammonium sulfate ((NH4)2SO4) complexes and electrochemical cell performance

被引：68

作者：

Ali, AMM ^{[1
]}

Mohamed, NS ^{[1
]}

Arof, AK ^{[1
]}

机构：

[1] Univ Malaya, Ctr Fdn Studies Sci, Div Phys, Kuala Lumpur 50603, Malaysia

来源：

JOURNAL OF POWER SOURCES | 1998年 / 74卷 / 01期

关键词：

electrochemical cell; polymer; electrolyte; polyethylene oxide; ammonium sulfate; solid-state;

D O I：

10.1016/S0378-7753(98)00045-7

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The PEO-(NH4)(2)SO4 systems with different NH4+/EO ratio have been prepared by the solution-cast technique and investigated by X-ray diffraction, infrared spectroscopy and impedance spectroscopy. The highest conductivity (2.7 x 10(-6) S cm(-1)) is obtained from the film with a NH4+/EO ratio of 0.050. Some electrochemical cells are then fabricated using the film with the highest electrical conductivity as the electrolyte. Different metal oxides and their combination are used as the cathode active materials. The highest open-circuit voltage (OCV) of 1.059 V is provided by the cell with configuration (Zn + ZnSO4. 7H(2)O)/PEO-(NH4)(2)SO4/(0.02 g PbO2 + 0.02 g MnO2). The short-circuit current of this cell is 97 mu A. (C) 1998 Elsevier Science S.A. All rights reserved.

引用

页码：135 / 141

页数：7

共 18 条

[11] CONDUCTIVITY AND STRUCTURAL STUDIES OF PEO-NH4SCN ELECTROLYTES [J].

PRUSINOWSKA, D ;

WIECZOREK, W ;

WYCISLIK, H ;

SIEKIERSKI, M ;

PRZYLUSKI, J ;

SOLTYSIAK, J .

SOLID STATE IONICS, 1994, 72 :152-159

[12] IONIC-CONDUCTIVITY AND BATTERY CHARACTERISTIC STUDIES ON PEO+AGNO3 POLYMER ELECTROLYTE [J].

RAO, SS ;

RAO, KVS ;

SHAREEFUDDIN, M ;

RAO, UVS ;

CHANDRA, S .

SOLID STATE IONICS, 1994, 67 (3-4) :331-334

[13] SOLID POLYMER ELECTROLYTES BASED ON POLYETHYLENE OXIDE-SILVER THIOCYANATE [J].

SEKHON, SS ;

SINGH, G ;

AGNIHOTRY, SA ;

CHANDRA, S .

SOLID STATE IONICS, 1995, 80 (1-2) :37-44

[14] PERFORMANCE OF A SOLID-STATE BATTERY WITH A PROTON CONDUCTING ELECTROLYTE [J].

SINGH, K ;

TIWARI, RU ;

DESHPANDE, VK .

JOURNAL OF POWER SOURCES, 1993, 46 (01) :65-71

[15]

Srivastava N, 1996, SOLID STATE IONICS N, P411

[16] STOICHIOMETRY OF FORMATION AND CONDUCTIVITY RESPONSE OF AMORPHOUS AND CRYSTALLINE COMPLEXES FORMED BETWEEN POLY(ETHYLENE OXIDE) AND AMMONIUM-SALTS - PEOX.NH4SCN AND PEOX.NH4SO3CF3 [J].

STAINER, M ;

HARDY, LC ;

WHITMORE, DH ;

SHRIVER, DF .

JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 1984, 131 (04) :784-790

[17]

Wright P. V., 1975, British Polymer Journal, V7, P319, DOI 10.1002/pi.4980070505

[18]

[No title captured]

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